A thermodynamic connection to the fragility of glass-forming liquids
LM Martinez, CA Angell - Nature, 2001 - nature.com
Although liquids normally crystallize on cooling, there are members of all liquid types
(including molecular, ionic and metallic) that supercool and then solidify at their glass …
(including molecular, ionic and metallic) that supercool and then solidify at their glass …
Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
K Ito, CT Moynihan, CA Angell - Nature, 1999 - nature.com
If crystallization can be avoided when a liquid is cooled, it will typically form a glass. Near the
glass transition temperature the viscosity increases continuously but rapidly with cooling. As …
glass transition temperature the viscosity increases continuously but rapidly with cooling. As …
The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids
S Sastry - Nature, 2001 - nature.com
Glass is a microscopically disordered, solid form of matter that results when a fluid is cooled
or compressed in such a manner that it does not crystallize. Almost all types of materials are …
or compressed in such a manner that it does not crystallize. Almost all types of materials are …
Liquid landscape
A Angell - Nature, 1998 - nature.com
Supercooled liquids—at temperatures below their normal freezing point—can undergo a
subtle transition to a microscopically fixed, yet amorphous, state: a glass. The temperature of …
subtle transition to a microscopically fixed, yet amorphous, state: a glass. The temperature of …
Signatures of distinct dynamical regimes in the energy landscape of a glass-forming liquid
S Sastry, PG Debenedetti, FH Stillinger - Nature, 1998 - nature.com
Most materials attain a glassy state at low temperatures under suitable methods of
preparation. This state exhibits the mechanical properties of a solid, but shows microscopic …
preparation. This state exhibits the mechanical properties of a solid, but shows microscopic …
Poisson's ratio and the fragility of glass-forming liquids
VN Novikov, AP Sokolov - Nature, 2004 - nature.com
The nature of the transformation by which a supercooled liquid 'freezes' to a glass—the
glass transition—is a central issue in condensed matter physics,, but also affects many other …
glass transition—is a central issue in condensed matter physics,, but also affects many other …
Phonon interpretation of the 'boson peak'in supercooled liquids
Glasses, are amorphous solids, in the sense that they display elastic behaviour. In
crystalline solids, elasticity is associated with phonons, which are quantized vibrational …
crystalline solids, elasticity is associated with phonons, which are quantized vibrational …
Growing range of correlated motion in a polymer melt on cooling towards the glass transition
C Bennemann, C Donati, J Baschnagel, SC Glotzer - Nature, 1999 - nature.com
Many liquids cooled to low temperatures form glasses (amorphous solids) instead of
crystals. As the glass transition is approached, molecules become localized and relaxation …
crystals. As the glass transition is approached, molecules become localized and relaxation …
Soft colloids make strong glasses
J Mattsson, HM Wyss, A Fernandez-Nieves, K Miyazaki… - Nature, 2009 - nature.com
Glass formation in colloidal suspensions has many of the hallmarks of glass formation in
molecular materials,,,,. For hard-sphere colloids, which interact only as a result of excluded …
molecular materials,,,,. For hard-sphere colloids, which interact only as a result of excluded …
Supercooled liquids and the glass transition
PG Debenedetti, FH Stillinger - Nature, 2001 - nature.com
Glasses are disordered materials that lack the periodicity of crystals but behave
mechanically like solids. The most common way of making a glass is by cooling a viscous …
mechanically like solids. The most common way of making a glass is by cooling a viscous …