A thermodynamic connection to the fragility of glass-forming liquids

LM Martinez, CA Angell - Nature, 2001 - nature.com
Although liquids normally crystallize on cooling, there are members of all liquid types
(including molecular, ionic and metallic) that supercool and then solidify at their glass …

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water

K Ito, CT Moynihan, CA Angell - Nature, 1999 - nature.com
If crystallization can be avoided when a liquid is cooled, it will typically form a glass. Near the
glass transition temperature the viscosity increases continuously but rapidly with cooling. As …

The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids

S Sastry - Nature, 2001 - nature.com
Glass is a microscopically disordered, solid form of matter that results when a fluid is cooled
or compressed in such a manner that it does not crystallize. Almost all types of materials are …

Liquid landscape

A Angell - Nature, 1998 - nature.com
Supercooled liquids—at temperatures below their normal freezing point—can undergo a
subtle transition to a microscopically fixed, yet amorphous, state: a glass. The temperature of …

Signatures of distinct dynamical regimes in the energy landscape of a glass-forming liquid

S Sastry, PG Debenedetti, FH Stillinger - Nature, 1998 - nature.com
Most materials attain a glassy state at low temperatures under suitable methods of
preparation. This state exhibits the mechanical properties of a solid, but shows microscopic …

Poisson's ratio and the fragility of glass-forming liquids

VN Novikov, AP Sokolov - Nature, 2004 - nature.com
The nature of the transformation by which a supercooled liquid 'freezes' to a glass—the
glass transition—is a central issue in condensed matter physics,, but also affects many other …

Phonon interpretation of the 'boson peak'in supercooled liquids

TS Grigera, V Martín-Mayor, G Parisi, P Verrocchio - Nature, 2003 - nature.com
Glasses, are amorphous solids, in the sense that they display elastic behaviour. In
crystalline solids, elasticity is associated with phonons, which are quantized vibrational …

Growing range of correlated motion in a polymer melt on cooling towards the glass transition

C Bennemann, C Donati, J Baschnagel, SC Glotzer - Nature, 1999 - nature.com
Many liquids cooled to low temperatures form glasses (amorphous solids) instead of
crystals. As the glass transition is approached, molecules become localized and relaxation …

Soft colloids make strong glasses

J Mattsson, HM Wyss, A Fernandez-Nieves, K Miyazaki… - Nature, 2009 - nature.com
Glass formation in colloidal suspensions has many of the hallmarks of glass formation in
molecular materials,,,,. For hard-sphere colloids, which interact only as a result of excluded …

Supercooled liquids and the glass transition

PG Debenedetti, FH Stillinger - Nature, 2001 - nature.com
Glasses are disordered materials that lack the periodicity of crystals but behave
mechanically like solids. The most common way of making a glass is by cooling a viscous …