Supramolecular template-assisted catalytic [2+ 2] photocycloaddition in homogeneous solution

F Wang, S Bai, QW Zhu, ZH Wei, YF Han - CCS Chemistry, 2023 - chinesechemsoc.org
Supramolecular interactions can help recognize and organize substrates around an
enzyme's active sites and subsequently assemble a new molecule in a certain way. Inspired …

Coordination-driven self-assembly of anthraquinone-based metal–organic cages for photocatalytic selective [2+ 2] cycloaddition

Y Jin, H Jiang, X Tang, W Zhang, Y Liu, Y Cui - Dalton Transactions, 2021 - pubs.rsc.org
Visible-light-promoted [2+ 2] cycloaddition provides a straightforward and efficient way to
produce cyclobutanes, which are the core skeleton in commercial pharmaceuticals and fine …

Cage-confined photocatalysis for wide-scope unusually selective [2+ 2] cycloaddition through visible-light triplet sensitization

JS Wang, K Wu, C Yin, K Li, Y Huang, J Ruan… - Nature …, 2020 - nature.com
Abstract Light-induced [2+ 2] cycloaddition is the most straightforward way to generate
cyclobutanes, which are core structures of many natural products, drugs and bioactive …

Anion-Mediated Allosteric Catalysis of [2+ 2] Photocycloaddition Based on a Flexible Metallo-Amine Cage for High Diastereoselectivity

YL Lu, YH Qin, SP Zheng, J Ruan, YH Huang… - ACS …, 2023 - ACS Publications
Anions can exert a notable influence on the solubility and folding of protein structures,
consequently altering their activity and stability due to the well-known Hofmeister effect …

Photocatalytic regioselective and stereoselective [2+ 2] cycloaddition of styrene derivatives using a heterogeneous organic photocatalyst

R Li, BC Ma, W Huang, L Wang, D Wang, H Lu… - ACS …, 2017 - ACS Publications
Photocatalytic [2+ 2] cycloaddition is a useful tool for the synthesis of cyclobutane
derivatives, which contributes a large part to natural compound production. Usually, the [2+ …

Enantioselective [2+ 2] Cross-Photocycloaddition Enabled by a Chiral Cage Reactor via Multilevel-Selectivity Control

J Ruan, Z Li, C Yin, YL Lu, ZW Wei, P Hu, CY Su - ACS Catalysis, 2024 - ACS Publications
In the recently burgeoning field of asymmetric [2+ 2] photocycloaddition, a challenging
hurdle lies in achieving a multilevel control of chemo-, regio-, diastereo-, and …

Visible light-mediated intermolecular crossed [2+ 2] cycloadditions using a MOF-supported copper triplet photosensitizer

J Guo, Q Xia, WY Tang, Z Li, X Wu, LJ Liu, WP To… - Nature Catalysis, 2024 - nature.com
Abstract The photochemical [2+ 2] cycloaddition of styrenes provides a frequently used route
for the synthesis of multi-substituted cyclobutanes. Despite the extensive studies in noble …

Photocatalytic [3+ 2] Cycloaddition of Alkyl/aryl Iodides and Internal Alkynes by Merging Halogen and Hydrogen Atom Transfer

Z Gu, R Jia, T Zeng, H Zheng… - Chinese Journal of …, 2024 - Wiley Online Library
Comprehensive Summary A visible light photocatalytic [3+ 2] cycloaddition of alkynes with
readily accessible organic iodides as the C3 synthon is developed herein. By merging …

Aggregation-enabled intermolecular photo [2+ 2] cycloaddition of aryl terminal olefins by visible-light catalysis

Z Liu, C Zhou, T Lei, XL Nan, B Chen… - CCS …, 2020 - chinesechemsoc.org
Photo [2+ 2] cycloaddition of olefins is a sought-after tool for making cyclobutanes, which are
the building blocks for a wide range of biologically active molecules and natural products …

Carboxylic acid and metal ion co-driven assembly of triene coordination polymers for [2+ 2] photocycloaddition

XR Xue, C Cao, Y Ge, QY Li, MJ Zhang, Q Liu… - Inorganic Chemistry …, 2023 - pubs.rsc.org
The application of coordination polymers (CPs) as a platform to control the arrangement of
olefin-containing ligands to produce cyclobutane derivatives by [2+ 2] photocycloaddition …