Robust electrografted interfaces on metal oxides for electrocatalysis–an in situ spectroelectrochemical study
TGAA Harris, R Götz, P Wrzolek, V Davis… - Journal of Materials …, 2018 - pubs.rsc.org
Diazonium salts were electrografted onto transparent conductive oxides as stable
alternatives to conventional anchoring groups for the surface immobilisation of molecular …
alternatives to conventional anchoring groups for the surface immobilisation of molecular …
Electrodeposition of Fe-complexes on oxide surfaces for efficient OER catalysis
Progress in non-covalent/self-assembled immobilization methods on (photo) electrode
materials for molecular catalysts could broaden the scope of attainable systems. While …
materials for molecular catalysts could broaden the scope of attainable systems. While …
Designing stable redox-active surfaces: chemical attachment of an osmium complex to glassy carbon electrodes prefunctionalized by electrochemical reduction of an …
The production of stable redox-active layers on electrode surfaces can lead to improvements
in electronic device design. Enhanced stability can be achieved by pretreatment of electrode …
in electronic device design. Enhanced stability can be achieved by pretreatment of electrode …
Tuning electrode reactivity through organometallic complexes
The use of molecularly modified electrodes in catalysis heralds a new paradigm in
designing chemical transformations by allowing control of catalytic activity. Herein, we …
designing chemical transformations by allowing control of catalytic activity. Herein, we …
Electrografted interfaces on metal oxide electrodes for enzyme immobilization and bioelectrocatalysis
In this work, we demonstrate that diazonium electrografting of biocompatible interfaces on
transparent conducting oxide indium tin oxide (ITO) can be controlled and optimized to …
transparent conducting oxide indium tin oxide (ITO) can be controlled and optimized to …
Expanding the Redox Range of Surface-Immobilized Metallocomplexes Using Molecular Interfaces
BL Wadsworth, D Khusnutdinova… - … applied materials & …, 2019 - ACS Publications
Rationally designed material interfaces offer opportunities to control matter and energy
across multiple length scales, yet remain challenging to synthetically prepare. Inspired by …
across multiple length scales, yet remain challenging to synthetically prepare. Inspired by …
Electrifying Oxide Model Catalysis: Complex Electrodes Based on Atomically-Defined Oxide Films
By studying complex model catalysts based on well-defined oxide surfaces, fundamental
insights have been obtained into the surface chemistry of many heterogeneously catalyzed …
insights have been obtained into the surface chemistry of many heterogeneously catalyzed …
Condensed Layer Deposition of Nanoscopic TiO2 Overlayers on High-Surface-Area Electrocatalysts
Encapsulating an electrocatalytic material with a semipermeable, nanoscopic oxide
overlayer offers a promising approach to enhancing its stability, activity, and/or selectivity …
overlayer offers a promising approach to enhancing its stability, activity, and/or selectivity …
Electrocatalysis on oxide surfaces: Fundamental challenges and opportunities
AR Akbashev - Current Opinion in Electrochemistry, 2022 - Elsevier
Oxides are often perceived as relatively simple materials that can provide exceptional
electrocatalytic activities. However, the assumed simplicity of oxides bears little relation to …
electrocatalytic activities. However, the assumed simplicity of oxides bears little relation to …
Angstrom-resolved real-time dissection of electrochemically active noble metal interfaces
BR Shrestha, T Baimpos, S Raman, M Valtiner - ACS nano, 2014 - ACS Publications
Electrochemical solid| liquid interfaces are critically important for technological applications
and materials for energy storage, harvesting, and conversion. Yet, a real-time Angstrom …
and materials for energy storage, harvesting, and conversion. Yet, a real-time Angstrom …