Robust electrografted interfaces on metal oxides for electrocatalysis–an in situ spectroelectrochemical study

TGAA Harris, R Götz, P Wrzolek, V Davis… - Journal of Materials …, 2018 - pubs.rsc.org
Diazonium salts were electrografted onto transparent conductive oxides as stable
alternatives to conventional anchoring groups for the surface immobilisation of molecular …

Electrodeposition of Fe-complexes on oxide surfaces for efficient OER catalysis

SM Al-Zuraiji, T Benkó, K Frey, Z Kerner, JS Pap - Catalysts, 2021 - mdpi.com
Progress in non-covalent/self-assembled immobilization methods on (photo) electrode
materials for molecular catalysts could broaden the scope of attainable systems. While …

Designing stable redox-active surfaces: chemical attachment of an osmium complex to glassy carbon electrodes prefunctionalized by electrochemical reduction of an …

S Boland, F Barrière, D Leech - Langmuir, 2008 - ACS Publications
The production of stable redox-active layers on electrode surfaces can lead to improvements
in electronic device design. Enhanced stability can be achieved by pretreatment of electrode …

Tuning electrode reactivity through organometallic complexes

Y Shen, Y Mu, D Wang, C Liu… - ACS applied materials & …, 2023 - ACS Publications
The use of molecularly modified electrodes in catalysis heralds a new paradigm in
designing chemical transformations by allowing control of catalytic activity. Herein, we …

Electrografted interfaces on metal oxide electrodes for enzyme immobilization and bioelectrocatalysis

TGAA Harris, N Heidary, S Frielingsdorf… - …, 2021 - Wiley Online Library
In this work, we demonstrate that diazonium electrografting of biocompatible interfaces on
transparent conducting oxide indium tin oxide (ITO) can be controlled and optimized to …

Expanding the Redox Range of Surface-Immobilized Metallocomplexes Using Molecular Interfaces

BL Wadsworth, D Khusnutdinova… - … applied materials & …, 2019 - ACS Publications
Rationally designed material interfaces offer opportunities to control matter and energy
across multiple length scales, yet remain challenging to synthetically prepare. Inspired by …

Electrifying Oxide Model Catalysis: Complex Electrodes Based on Atomically-Defined Oxide Films

O Brummel, J Libuda - Catalysis Letters, 2020 - Springer
By studying complex model catalysts based on well-defined oxide surfaces, fundamental
insights have been obtained into the surface chemistry of many heterogeneously catalyzed …

Condensed Layer Deposition of Nanoscopic TiO2 Overlayers on High-Surface-Area Electrocatalysts

DV Fraga Alvarez, Z Lin, Z Shi, AF Baxter… - … Applied Materials & …, 2024 - ACS Publications
Encapsulating an electrocatalytic material with a semipermeable, nanoscopic oxide
overlayer offers a promising approach to enhancing its stability, activity, and/or selectivity …

Electrocatalysis on oxide surfaces: Fundamental challenges and opportunities

AR Akbashev - Current Opinion in Electrochemistry, 2022 - Elsevier
Oxides are often perceived as relatively simple materials that can provide exceptional
electrocatalytic activities. However, the assumed simplicity of oxides bears little relation to …

Angstrom-resolved real-time dissection of electrochemically active noble metal interfaces

BR Shrestha, T Baimpos, S Raman, M Valtiner - ACS nano, 2014 - ACS Publications
Electrochemical solid| liquid interfaces are critically important for technological applications
and materials for energy storage, harvesting, and conversion. Yet, a real-time Angstrom …