Formation of C–C and C–heteroatom bonds by C–H activation by metal organic frameworks as catalysts or supports

A Dhakshinamoorthy, AM Asiri, H Garcia - ACS Catalysis, 2018 - ACS Publications
Cross-coupling reactions catalyzed by transition metals are currently among the most widely
used transformations in organic synthesis. In most of these reactions, the coupling involves …

Kinetic and X-ray Absorption Spectroscopic Analysis of Catalytic Redox Cycles over Highly Uniform Polymetal Oxo Clusters

JN Hall, AJ Kropf, M Delferro, P Bollini - ACS Catalysis, 2023 - ACS Publications
Metal–organic framework materials (MOFs) offer an opportunity for investigating catalytic
properties of polymetal oxo clusters that are highly well defined and uniform in nature, in …

Mechanism and selectivity of MOF-supported Cu single-atom catalysts for preferential CO oxidation

S Impeng, E Salaya-Gerónimo, B Kunkel… - Journal of Materials …, 2024 - pubs.rsc.org
Zr-based UiO-66 metal–organic frameworks are ideal platforms for the design and
development of heterogeneous single-atom catalysts (SACs) because of their thermal and …

Accelerated computational analysis of metal–organic frameworks for oxidation catalysis

KD Vogiatzis, E Haldoupis, DJ Xiao… - The Journal of …, 2016 - ACS Publications
High-spin iron (IV)–oxo compounds are known to activate strong C–H bonds. Stabilizing the
high-spin S= 2 electronic configuration is difficult in molecular species for homogeneous …

[HTML][HTML] Unraveling reaction networks behind the catalytic oxidation of methane with H 2 O 2 over a mixed-metal MIL-53 (Al, Fe) MOF catalyst

Á Szécsényi, G Li, J Gascon, EA Pidko - Chemical science, 2018 - pubs.rsc.org
Reaction paths underlying the catalytic oxidation of methane with H2O2 over an Fe
containing MIL-53 (Al) metal–organic framework were studied by periodic DFT calculations …

Catalytic CO Oxidation by Cu Single Atoms on the UiO-66 Metal–Organic Framework: The Role of the Oxidation State

MR Yousuf, EM Johnson, AJ Maynes… - The Journal of …, 2022 - ACS Publications
Recent experiments have demonstrated catalysis by single transition-metal atoms supported
on metal–organic frameworks (MOF) but have yet to decipher the role of the transition-metal …

A modelling approach for MOF-encapsulated metal catalysts and application to n-butane oxidation

DA Gomez-Gualdron, ST Dix, RB Getman… - Physical Chemistry …, 2015 - pubs.rsc.org
Metal nanoparticles (NP) encapsulated by metal–organic frameworks (MOFs) are novel
composite materials that have shown promise as regioselective catalysts. The …

Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions

YB Huang, J Liang, XS Wang, R Cao - Chemical Society Reviews, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs) are porous crystalline materials constructed from metal
ions or clusters and multidentate organic ligands. Recently, the use of MOFs or MOF …

Structural Evolution of Iron-Loaded Metal–Organic Framework Catalysts for Continuous Gas-Phase Oxidation of Methane to Methanol

B Rungtaweevoranit, AM Abdel-Mageed… - … Applied Materials & …, 2023 - ACS Publications
Catalytic partial oxidation of methane presents a promising route to convert the abundant but
environmentally undesired methane gas to liquid methanol with applications as an energy …

Engineering metal–organic framework catalysts for C− C and C− X coupling reactions: advances in reticular approaches from 2014–2018

S Kousik, S Velmathi - Chemistry–A European Journal, 2019 - Wiley Online Library
Metal–organic frameworks (MOFs) are a class of crystalline porous materials that have been
actively used for several industrial and synthetic applications. MOFs are spatially and …