As the main component of natural and shale gas, seabed clathrates, and biogas, methane
(CH 4) is an abundant C1 resource for added-value chemicals. CH 4 is of critical importance …

In contrast to catalytically active metal single atoms deposited on oxide nanoparticles, the
crystalline nature of metal‐organic frameworks (MOFs) allows for a thorough …

Iron-based enzymes efficiently activate molecular oxygen to perform the oxidation of
methane to methanol (MTM), a reaction central to the contemporary chemical industry …

Metal–organic framework (MOF)-encapsulated single-atom metal catalysts (SACs), as a
bridge between homogeneous and heterogeneous catalysts, have received extensive …

Selective oxidation of C–H bonds under mild conditions is one of the most important and
challenging issues in utilization of energy-related molecules. Molybdenum oxide …

Reactive oxygen species (ROS) are highly reactive molecules derived from oxygen, which
are naturally generated and play essential roles in biological processes. At the same time …

Clarity as to the role of metal identity and oxidation state in effecting redox and acid‐
catalyzed turnovers is oftentimes precluded by a high degree of heterogeneity in site …

Porous metal–organic frameworks (MOFs) are built from periodically alternate organic
moieties and metal ions/clusters. The unique features of the open framework structures, the …

The challenge of activating inert C–H bonds motivates a study of catalysts that draws from
what can be accomplished by natural enzymes and translates these advantageous features …

We investigate the potential use of Fe (IV) oxo species supported on a metal–organic
framework in the catalytic hydroxylation of methane to produce methanol. We use periodic …