Field-Induced Single Molecule Magnetic Behavior of Mononuclear Cobalt (II) Schiff Base Complex Derived from 5-Bromo Vanillin

F Elemo, S Schlittenhardt, T Sani, C Rajnák, W Linert… - Inorganics, 2022 - mdpi.com
A mononuclear Co (II) complex of a Schiff base ligand derived from 5-Bromo-vanillin and 4-
aminoantipyrine, that has a compressed tetragonal bipyramidal geometry and exhibiting …

Coordination number impact on magnetic properties of Schiff base Co (II) complexes

A Gusev, Y Baluda, AK Matiukhina, M Kiskin, W Linert - Polyhedron, 2024 - Elsevier
Two mononuclear Co (II) complexes with a tetrahedral and octahedral coordination
geometry with a Schiff base ligand L−(anion of 4-[(2-fluoroanilino)-phenyl-methylene]-5 …

Modulation of the Coordination Environment around the Magnetic Easy Axis Leads to Significant Magnetic Relaxations in a Series of 3d-4f Schiff Complexes

JW Yang, YM Tian, J Tao, P Chen, HF Li… - Inorganic …, 2018 - ACS Publications
A series of Salen-type Zn (II)–Dy (III) complexes [L1Zn (II) ClDy (III)(acac) 2]· H2O (1),[L1Zn
(II) BrDy (III)(acac) 2]· H2O (2),[L1Zn (II)(H2O) Dy (III)(acac) 2]· CH2Cl2· PF6 (3),[L2Zn …

Field-induced single-molecule magnet behaviour in a series of dinuclear cobalt (III, II) complexes

A Banerjee, CJG García, S Benmansour, RM Gomlia… - Polyhedron, 2022 - Elsevier
We present the synthesis, structure and magnetic characterization of four dinuclear cobalt
(III, II) complexes:[(NCS) Co III (L n)(µ–OAc) Co II (NCS)]· G, with n/G= 1/CH 3 OH (1), 2/CH 3 …

Ligand‐field effect to harness the magnetic anisotropy in a series of mixed valence Co (III)–Co (II) dinuclear complexes

EM Manohar, T Guizouarn, N Ahmed… - Applied …, 2024 - Wiley Online Library
Three mixed valence dinuclear Co (III)–Co (II)‐based complexes having general formulae of
[CoIICoIII (HL2) 2 (L1)][L1H= 2‐hydroxy‐1‐naphthaldehyde (1), o‐vanillin (2), and …

Slow magnetic relaxation for cobalt (II) complexes in axial bipyramidal environment: an S= 1/2 spin case

E Pilichos, M Font-Bardia, J Cano, A Escuer… - Dalton …, 2022 - pubs.rsc.org
A new family of magnetically mononuclear cobalt (II) complexes with formula [{NiII (L) CoII
(H2O) 2 (MeOH)}{NiII (L)} 2](ClO4) 2 where H2L1= bis (N, N′-bis (3-methoxysalicylidene) …

Syntheses, crystal structures and magnetic properties of two mixed-valence Co (III) Co (II) compounds derived from Schiff base ligands: field-supported single-ion …

S Mandal, S Mondal, C Rajnák, J Titiš, R Boča… - Dalton …, 2017 - pubs.rsc.org
Two μ-phenoxo-μ1, 1-azide dinuclear CoIIICoII complexes [CoIII (N3) 2L1 (μ1, 1-N3) CoII
(N3)]· MeOH (1) and [CoIII (N3) 2L2 (μ1, 1-N3) CoII (N3)]· MeOH (2)(HL1 and HL2 are two …

Observation of field-induced single-molecule magnet behavior in an octahedrally coordinated binuclear Co2 compound

J Du, J Tian, B Li, Z Yang, L Sun, B Duan, P Ma… - Inorganica Chimica …, 2022 - Elsevier
A binuclear cobalt compound, namely,[Co 2 (L) 2 Cl 2 (H 2 O) 4]· 2Cl· 2H 2 O (1), was
synthesized by acylhydrazone Schiff base ligand N 3-(4-pyridyl)-4 …

Zero-field slow magnetic relaxation from single Co (II) ion: a transition metal single-molecule magnet with high anisotropy barrier

YY Zhu, C Cui, YQ Zhang, JH Jia, X Guo, C Gao… - Chemical …, 2013 - pubs.rsc.org
An air-stable star-shaped CoIICoIII3 complex with only one paramagnetic Co (II) ion in the
D3 coordination environment has been synthesized from a chiral Schiff base ligand …

Field-assisted slow magnetic relaxation in a six-coordinate Co (II)–Co (III) complex with large negative anisotropy

EA Buvaylo, VN Kokozay, OY Vassilyeva… - Inorganic …, 2017 - ACS Publications
The reaction of Co (CH3COO) 2· 4H2O with the Schiff base ligand LH4 derived from o-
vanillin and tris (hydroxymethyl) aminomethane produces the dinuclear mixed-valence …