On mechanisms of mesocrystal formation: Magnesium ions and water environments regulate the crystallization of amorphous minerals

YC Huang, MB Gindele, J Knaus, A Rao, D Gebauer - CrystEngComm, 2018 - pubs.rsc.org
Nature produces hierarchical, functional materials by shaping amorphous mineral
precursors under physiological conditions. Although biominerals inspire the architectures of …

Mineralization schemes in the living world: mesocrystals

A Rao, H Cölfen - New perspectives on mineral nucleation and growth …, 2017 - Springer
With the expanding knowledge on structure–property relations in biogenic minerals, an
emerging challenge is to decipher the underlying biochemical and physical mechanisms of …

Unveiling the critical process in which organic molecules control the polymorphism of magnesium-containing calcium carbonate: the early nucleation of amorphous …

J Xiao, S Yang - CrystEngComm, 2011 - pubs.rsc.org
Mineralization can be divided into the nucleation of amorphous precursors and the
subsequent amorphous to crystalline transformation. Although the biomimetic …

Understanding Hierarchical Structure Construction Strategies and Biomimetic Design Principles: A Review

S Jia, T Tao, J Sun, J Du, Y Xie, L Yu, W Tang… - Small …, 2023 - Wiley Online Library
Organisms use gene and cell engineering to tailor the mineralization process and
synthesize structure composites with special functions and favorable properties. This spurs …

Solid-state phase transformation and self-assembly of amorphous nanoparticles into higher-order mineral structures

S Von Euw, T Azaïs, V Manichev… - Journal of the …, 2020 - ACS Publications
Materials science has been informed by nonclassical pathways to crystallization, based on
biological processes, about the fabrication of damage-tolerant composite materials. Various …

Shape-preserving amorphous-to-crystalline transformation of CaCO3 revealed by in situ TEM

Z Liu, Z Zhang, Z Wang, B Jin, D Li… - Proceedings of the …, 2020 - National Acad Sciences
Organisms use inorganic ions and macromolecules to regulate crystallization from
amorphous precursors, endowing natural biominerals with complex morphologies and …

Phosphate–water interplay tunes amorphous calcium carbonate metastability: Spontaneous phase separation and crystallization vs stabilization viewed by solid state …

S Kababya, A Gal, K Kahil, S Weiner… - Journal of the …, 2015 - ACS Publications
Organisms tune the metastability of amorphous calcium carbonates (ACC), often by
incorporation of additives such as phosphate ions and water molecules, to serve diverse …

Pseudo-biomineralization: Complex mineral structures shaped by microbes

GM Durak, M Laumann, SLP Wolf… - ACS Biomaterials …, 2019 - ACS Publications
Biomineralization is an active, biologically governed process of mineral formation,
established early on in the history of life. The appearance of biomineralizing organisms …

From molecular level to macroscopic properties: A solid-state NMR biomineralization and biomimetic exploration

S Kababya, IB Shir, A Schmidt - Current Opinion in Colloid & Interface …, 2022 - Elsevier
Through biomineralization, calcareous composites are produced with exceptional
properties, evolution-optimized for specific function. The bioinspired quest to understand …

[HTML][HTML] Amorphous phase mediated crystallization: Fundamentals of biomineralization

W Jin, S Jiang, H Pan, R Tang - Crystals, 2018 - mdpi.com
Many biomineralization systems start from transient amorphous precursor phases, but the
exact crystallization pathways and mechanisms remain largely unknown. The study of a well …