Copper complexation in the Northeast Pacific

KH Coale, KW Bruland - Limnology and Oceanography, 1988 - Wiley Online Library
Copper titrations were conducted at sea with differential pulse anodic stripping voltammetry
to examine the degree to which copper was associated with organic ligands. Greater than …

Spatial and temporal variability in copper complexation in the North Pacific

KH Coale, KW Bruland - Deep Sea Research Part A. Oceanographic …, 1990 - Elsevier
The complexation of trace metals by organic ligands has long been proposed to play a
significant role in determining trace metal speciation in seawater. However, analytical …

Acquisition of organically complexed copper by marine phytoplankton and bacteria in the northeast subarctic Pacific Ocean

DM Semeniuk, RM Bundy, CD Payne, KA Barbeau… - Marine Chemistry, 2015 - Elsevier
Copper (Cu) is an essential micronutrient for marine phytoplankton, but can cause toxicity at
elevated intracellular concentrations. The majority of Cu (> 99.9%) in oceanic surface waters …

Copper-binding ligands in deep-sea pore waters of the Pacific Ocean and potential impacts of polymetallic nodule mining on the copper cycle

SAL Paul, R Zitoun, A Noowong, M Manirajah… - Scientific reports, 2021 - nature.com
The release of potentially toxic metals, such as copper (Cu), into the water column is of
concern during polymetallic nodule mining. The bioavailability and thus toxicity of Cu is …

Fluxes of strong Cu-complexing ligands from sediments of an organic-rich estuary

GC Shank, SA Skrabal, RF Whitehead… - Estuarine, Coastal and …, 2004 - Elsevier
Benthic fluxes were evaluated as a source of strong Cu-complexing ligands (K′ CuL>
1011) to the water column of the organic-rich Cape Fear River estuary along the North …

Dissolved copper isotope biogeochemistry in the Tasman Sea, SW Pacific Ocean

CM Thompson, MJ Ellwood - Marine Chemistry, 2014 - Elsevier
Described as a 'Goldilocks element'in seawater, the free copper ion (Cu 2+) concentration in
open ocean waters is generally low enough to avoid causing toxicity to marine algae and …

Dissolved and colloidal copper in the tropical South Pacific

S Roshan, J Wu - Geochimica et Cosmochimica Acta, 2018 - Elsevier
Copper (Cu) as a bioactive trace metal in the ocean has widely been studied in the context
of chemical speciation. However, this trace metal is extremely understudied in the context of …

A review of chemical speciation techniques used for predicting dissolved copper bioavailability in seawater

P Sánchez-Marín - Environmental Chemistry, 2020 - CSIRO Publishing
Environmental context Copper (Cu) is a metal of ecotoxicological concern in contaminated
coastal areas. Cu present as the free ion is considered the most bioavailable fraction of the …

Organic Cu-complexation at the shallow marine hydrothermal vent fields off the coast of Milos (Greece), Dominica (Lesser Antilles) and the Bay of Plenty (New …

C Kleint, S Kuzmanovski, Z Powell, SI Bühring… - Marine Chemistry, 2015 - Elsevier
Hydrothermal vents at the seafloor release large volumes of metal-rich fluids into the ocean.
Some of these metals are biologically essential (such as Fe), while others may be toxic (eg …

Dissolved concentrations and organic speciation of copper in the Amazon River estuary and mixing plume

AP Hollister, H Whitby, M Seidel, P Lodeiro, M Gledhill… - Marine Chemistry, 2021 - Elsevier
Abstract The Amazon is Earth's largest river by volume output, making it an important source
of trace metals and dissolved organic matter (DOM) to the Atlantic Ocean. Despite major …