New insights into the organic complexation of bioactive trace metals in the global ocean from the GEOTRACES era

H Whitby, J Park, Y Shaked, RM Boiteau, KN Buck… - Oceanography, 2024 - JSTOR
The GEOTRACES program has greatly expanded measurements of dissolved trace metal
concentrations across ocean basins, but to understand the behavior and cycling of metals …

A review of total dissolved copper and its chemical speciation in San Francisco Bay, California

KN Buck, JRM Ross, AR Flegal, KW Bruland - Environmental Research, 2007 - Elsevier
Following basin-wide contamination from industrial emissions and urban development, total
dissolved copper concentrations in some regions of San Francisco Bay have exceeded …

Formation of Cu (I) in estuarine and marine waters: application of a new solid-phase extraction method to measure Cu (I)

D Buerge-Weirich, B Sulzberger - Environmental science & …, 2004 - ACS Publications
Cu (I) is a key species with respect to the bioavailability and hence toxicity of copper.
Therefore, it is important to elucidate the factors that control Cu (I) steady-state …

Copper complexation profiles in the Atlantic Ocean: A comparative study using electrochemical and ion exchange techniques

PJM Buckley, CMG van den Berg - Marine Chemistry, 1986 - Elsevier
The dissolved copper concentrations in several profiles of the water column in the Atlantic
Ocean were between 1 and 6 nM, and indicate copper removal from the surface layer and …

Trace metals in the open oceans: speciation modelling based on humic-type ligands

A Stockdale, E Tipping, J Hamilton-Taylor… - Environmental …, 2011 - CSIRO Publishing
Environmental context Speciation of trace metals in the oceans is typically explained by
invoking the concept of metal binding to specific organic ligands. Here, using a speciation …

Organic copper speciation by anodic stripping voltammetry in estuarine waters with high dissolved organic matter

J Pađan, S Marcinek, AM Cindrić, C Santinelli… - Frontiers in …, 2021 - frontiersin.org
The determination of copper (Cu) speciation and its bioavailability in natural waters is an
important issue due to its specific role as an essential micronutrient but also a toxic element …

Natural copper-binding ligands in the Arctic Ocean. The influence of the Transpolar Drift (GEOTRACES GN04)

V Arnone, JM Santana-Casiano… - Frontiers in Marine …, 2023 - frontiersin.org
The Arctic Ocean is a unique biogeochemical environment characterized by low salinity
surface waters, extensive sea-ice coverage, high riverine inputs, large shelf extension and …

The organic complexation of iron and copper: an intercomparison of competitive ligand exchange‐adsorptive cathodic stripping voltammetry (CLE‐ACSV) techniques

KN Buck, J Moffett, KA Barbeau… - Limnology and …, 2012 - Wiley Online Library
Characterization of the speciation of iron and copper is an important objective of the
GEOTRACES Science Plan. To incorporate speciation measurements into such a …

Interactions of trace elements and organic ligands in seawater and implications for quantifying biogeochemical dynamics: A review

J Zhang, G Kattner, BP Koch - Earth-science reviews, 2019 - Elsevier
Interactions between dissolved trace elements and organic ligands in seawater play an
important role in ocean biogeochemistry, ranging from regulating primary production in …

Speciation of dissolved copper and nickel in South San Francisco Bay: a multi-method approach

JR Donat, KA Lao, KW Bruland - Analytica Chimica Acta, 1994 - Elsevier
A multi-method approach was used to investigate the chemical speciation of dissolved
copper and nickel in South San Francisco Bay. Dissolved copper speciation was determined …