Dissociate transfer exchange of tandem dynamic bonds endows covalent adaptable networks with fast reprocessability and high performance

X Xu, S Ma, H Feng, J Qiu, S Wang, Z Yu, J Zhu - Polymer Chemistry, 2021 - pubs.rsc.org
Development of covalent adaptable networks (CANs) has connected thermosets and
thermoplastics and brought about various functions. However, combining the high …

Dual‐Dynamic Chemistries‐Based Fast‐Reprocessing and High‐Performance Covalent Adaptable Networks

K Hu, B Wang, X Xu, Y Su, W Zhang… - Macromolecular …, 2023 - Wiley Online Library
Covalent adaptable networks (CANs) possess multiple functions including reprocessing (or
recyclability), self‐healing, welding, shape shifting, 3D printing, etc., due to the network …

Fast‐Reprocessing, Postadjustable, Self‐Healing Covalent Adaptable Networks with Schiff Base and Diels–Alder Adduct

X Xu, S Ma, S Wang, B Wang, H Feng… - Macromolecular …, 2022 - Wiley Online Library
Covalent adaptable networks (CANs) are a new type of polymers, which possess excellent
performance of thermosets and reprocessability of thermoplastics. Nevertheless, it is still a …

Facile synthesis of hemiacetal ester-based dynamic covalent polymer networks combining fast reprocessability and high performance

H Feng, S Ma, X Xu, Q Li, B Wang, N Lu, P Li… - Green …, 2021 - pubs.rsc.org
Dynamic covalent polymer networks (DCPNs) can address the recycle or reuse issue of
thermosets due to their network rearrangement from the dynamic bond exchange. However …

Advancing Recyclable Thermosets through C═ C/C═ N Dynamic Covalent Metathesis Chemistry

J Zheng, H Feng, X Zhang, J Zheng… - Journal of the …, 2024 - ACS Publications
Thermoset polymers have become integral to our daily lives due to their exceptional
durability, making them feasible for a myriad of applications; however, this ubiquity also …

Mechanically robust and reprocessable imine exchange networks from modular polyester pre-polymers

RL Snyder, CAL Lidston, GX De Hoe… - Polymer …, 2020 - pubs.rsc.org
Covalent adaptable networks (CANs) containing reversible cross-links impart recyclability to
thermoset materials without sacrificing their desirable properties (eg high tensile strength …

Scalable and facile synthesis of acetal covalent adaptable networks with readily adjustable properties

N Lu, Q Li, S Ma, B Wang, X Xu, S Wang, J Ye… - European Polymer …, 2021 - Elsevier
Covalent adaptable networks (CANs) were rapidly developed to address the recycle issue of
thermosets; however, facile and scalable synthesis of CANs is still a challenge. Here, we …

Coded Interlocked Covalent Adaptable Networks Enabled by Parallel Connections of Cation− π Interactions and Aromatic Disulfide Bonds in Epoxy

L Zhou, L Zhou, R Chen, G Chang… - ACS Applied Polymer …, 2023 - ACS Publications
Covalent adaptable networks (CANs) that are cross-linked by reversible dynamic bonds
have been widely investigated, aiming at making the permanently cross-linked thermosets …

Thermomechanical activation achieving orthogonal working/healing conditions of nanostructured tri-block copolymer thermosets

RW Clarke, ML McGraw, BS Newell… - Cell Reports Physical …, 2021 - cell.com
Conventional thermosets, despite their technological significance in today's materials
economy, present a modern sustainability challenge because of their lack of end-of-life …

Fast reprocessing of acetal covalent adaptable networks with high performance enabled by neighboring group participation

Q Li, S Ma, P Li, B Wang, Z Yu, H Feng, Y Liu… - …, 2021 - ACS Publications
Covalent adaptable networks (CANs) represent a transition material combining favorable
features of thermosets and thermoplastics. However, it is still a huge challenge to …