Structural adaptability in an organic template for CaCO 3 mineralization

E DiMasi, SY Kwak, BP Pichon, NAJM Sommerdijk - CrystEngComm, 2007 - pubs.rsc.org
Biomimetic strategies to control mineral nucleation include the development of self-
assembled monolayers with appropriate structural properties. We present a bis-urea based …

Template Adaptability Is Key in the Oriented Crystallization of CaCO3

DC Popescu, MMJ Smulders, BP Pichon… - Journal of the …, 2007 - ACS Publications
In CaCO3, biomineralization nucleation and growth of the crystals are related to the
presence of carboxylate-rich proteins within a macromolecular matrix, often with organized β …

A Quasi-Time-Resolved CryoTEM Study of the Nucleation of CaCO3 under Langmuir Monolayers

BP Pichon, PHH Bomans, PM Frederik… - Journal of the …, 2008 - ACS Publications
Calcium carbonate biomineralization uses complex assemblies of macromolecules that
control the nucleation, growth, and positioning of the mineral with great detail. To investigate …

Patterning Inorganic (CaCO3) Thin Films via a Polymer-Induced Liquid-Precursor Process

YY Kim, EP Douglas, LB Gower - Langmuir, 2007 - ACS Publications
The biomimetic synthesis of patterned mineral thin films, based on a combination of the
microcontact printing technique and a novel crystallization process called the polymer …

When is template directed mineralization really template directed?

E DiMasi, MJ Olszta, VM Patel, LB Gower - CrystEngComm, 2003 - pubs.rsc.org
In-situ synchrotron X-ray scattering clarifies the role of templating on calcium carbonate
mineralization. Fatty acid monolayers are reorganized by Ca2+ in the subphase, into …

Calcite shape modulation through the lattice mismatch between the self-assembled monolayer template and the nucleated crystal face

B Pokroy, J Aizenberg - CrystEngComm, 2007 - pubs.rsc.org
The shapes of biologically formed calcite crystals are extremely versatile. Numerous studies
have addressed the possible biological mechanism of crystal shape regulation. Synthetic …

Hydrogels coupled with self-assembled monolayers: an in vitro matrix to study calcite biomineralization

H Li, LA Estroff - Journal of the American Chemical Society, 2007 - ACS Publications
This paper describes the control of the nucleation and growth of calcite crystals by a matrix
composed of an agarose hydrogel on top of a carboxylate-terminated self-assembled …

Control of crystal nucleation and growth of calcium carbonate by synthetic substrates

K Naka, Y Chujo - Chemistry of materials, 2001 - ACS Publications
Construction of organic− inorganic hybrid materials with controlled mineralization analogous
to those produced by nature is now of current interest for both organic and inorganic …

Crystal engineering of inorganic materials at organized organic surfaces

S Mann, BR Heywood, S Rajam, JBA Walker - 1991 - ACS Publications
The nucleation and growth of the mineral, CaCO3, under compressed Langmuir monolayers
has been studied by optical and electron microscopy and electron diffraction. The structure …

Polymer-controlled growth rate of an amorphous mineral film nucleated at a fatty acid monolayer

E DiMasi, VM Patel, M Sivakumar, MJ Olszta, YP Yang… - Langmuir, 2002 - ACS Publications
The nucleation and growth rate of an amorphous mineral film at a Langmuir monolayer
interface has been observed in situ with X-ray scattering techniques for the first time. We …