A novel access to phosphonic acids via Pd-catalyzed tandem carbon–phosphorus bond
formation–oxidation processes was developed. The procedures involve atom-economical …

A novel approach to H-phosphonates from hypophosphorous acid using a transfer
hydrogenation process was developed. This method is atom-economical, environmentally …

An azide and transition metal-free method for the synthesis of elusive phosphonic,
phosphinic, and phosphoric monoacids has been developed. Inert pentavalent P (V) …

A process for the conversion of hypophosphorous acid (H3PO2, HPA) and alcohols into
various H‐phosphonate diesters [(RO) 2P (O) H] is described. The new reaction provides a …

α-Aminophosphonates are synthesized by employing unfunctionalized starting materials
using cross-dehydrogenative coupling strategy. This method does not require any catalyst …

A novel base-promoted O-deprotonation/alkylation reaction of P (O)–OH compounds with
alkyl halides has been developed. The protocol is practical, representing a simple way to …

The chemistry of the hypophosphorous acid synthon, ethyl diethoxymethylphosphinate 1
has been further developed to afford efficient new routes to arylphosphinic acids 6 and 2 …

A new synthesis of unsymmetrical phosphinic acids R′ P (O) OHR ″has been evaluated.
The first P–C bond was formed by base‐promoted H‐phosphinate alkylation of a protected …

A versatile and environmentally friendly method for the synthesis of various
organophosphorus compounds have been developed using a heterogeneous catalysis …

Benzylic alcohols cross‐couple directly with concentrated H3PO2 by using Pd/xantphos (1
or 2 mol‐%). Depending on the substrate, DMF at 110° C or t‐AmOH at reflux with a Dean …