The isolation of formally two-coordinate lanthanide (Ln) complexes is synthetically
challenging, due to predominantly ionic Ln bonding regimes favoring high coordination …

Two mononuclear DyIII single-molecule magnets (SMMs) with C2v coordination symmetry
were synthesized. Both of them have strong uniaxial magnetic anisotropy with high effective …

Symmetry and axiality are thought to be guides toward the pursuit of high energy barrier and
blocking temperature for the dysprosium (III)(DyIII) single-molecule magnets (SMMs). The …

The combination of magnetic interaction with high magnetic anisotropy provides a promising
way for modulating/fine-tuning molecular magnetic behaviors. Here, we show the building …

Due to the large intrinsic magnetic anisotropy of the lanthanide ions, rare-earth metal
systems, and in particular dysprosium (Dy) based materials, have sparked increasing …

Targeted approaches for manipulating the coordination geometry of lanthanide ions are a
promising way to synthesize high-performance single-molecule magnets (SMMs), but most …

Single-molecule magnets (SMMs) are a fascinating class of molecular materials that display
slow relaxation of magnetization because of an intrinsic energy barrier (Ueff) to spin …

The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

A molecular dysprosium (III) complex [Dy (DClQ) 3 (H2O) 2](1) was used as a building unit
for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy (III) …

We report the synthesis of the lanthanide-(bis) boryloxide complex [Dy {OB (NArCH) 2} 2
(THF) 4][BPh4](2Dy, Ar= 2, 6-Pri2C6H3), with idealised D4h@ Dy (III) point-group symmetry …