Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

H Tian, BL Wang, J Lu, HT Liu, J Su, D Li… - Chemical …, 2018 - pubs.rsc.org
The double chloride-bridged dimer of a dinuclear dysprosium (III) single-molecule magnet
(SMM) was successfully isolated by assembling centrosymmetric dinuclear Dy2 SMMs. Such …

Significant enhancement of energy barriers in dinuclear dysprosium single-molecule magnets through electron-withdrawing effects

F Habib, G Brunet, V Vieru, I Korobkov… - Journal of the …, 2013 - ACS Publications
The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule
Magnets (SMMs) is investigated. By introducing highly electron-withdrawing atoms on …

Synthesis, crystal structure and magnetic properties of a dinuclear dysprosium single-molecule magnet

K Zhang, FS Guo, YY Wang - Inorganic Chemistry Communications, 2017 - Elsevier
To seek novel dysprosium based single-molecule magnets, a dinuclear dysprosium
complex, namely [Dy 2 (L) 2 (DBM) 2 (DMF) 2]· 2DMF (1) was successfully obtained by …

Counter anions influence the relaxation dynamics of phenoxy-bridged Dy 2 single molecule magnets

S Liu, J Lu, XL Li, Z Zhu, J Tang - Dalton Transactions, 2020 - pubs.rsc.org
The syntheses, structures and magnetic properties of a series of dimeric dysprosium (III)
complexes [Dy2L2 (CH3OH)(H2O)]· 2X· solvent {X= Cl (1), NO3 (2), ClO4 (3)} and [Dy2L2 …

Tuning the Magnetic Interactions and Relaxation Dynamics of Dy2 Single‐Molecule Magnets

S Xue, YN Guo, L Ungur, J Tang… - … –A European Journal, 2015 - Wiley Online Library
Efficient modulation of single‐molecule magnet (SMM) behavior was realized by deliberate
structural modification of the Dy2 cores of [Dy2 (a′ povh) 2 (OAc) 2 (DMF) 2](1) and …

Solvent Modification of the Structures and Magnetic Properties of a Series of Dysprosium (III) Single-Molecule Magnets

HQ Li, GL Wang, YC Sun, YQ Zhang… - Inorganic …, 2022 - ACS Publications
Solvent effects on the structures and magnetic properties of single-molecule magnets
(SMMs) have been of great interest for modification of the SMMs using chemical modulation …

Magnetic memory in an isotopically enriched and magnetically isolated mononuclear dysprosium complex

F Pointillart, K Bernot, S Golhen… - Angewandte …, 2015 - Wiley Online Library
The influence of nuclear spin on the magnetic hysteresis of a single‐molecule is evidenced.
Isotopically enriched DyIII complexes are synthesized and an isotopic dependence of their …

A dichlorido-bridged dinuclear Dy (III) single-molecule magnet with an effective energy barrier larger than 600 K

T Han, YS Ding, ZH Li, KX Yu, YQ Zhai… - Chemical …, 2019 - pubs.rsc.org
We report a dichlorido-bridged dinuclear dysprosium (III) single-molecule magnet [Dy
(Cy2N) 2 (μ-Cl)(THF)] 2 which shows an effective energy barrier for magnetization reversal …

Cis–trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets

J Wu, J Jung, P Zhang, H Zhang, J Tang… - Chemical …, 2016 - pubs.rsc.org
Geometry and magnetic relaxation modulations in a series of mononuclear dysprosium
complexes,[DyLz2 (o-vanilin) 2]· X· solvent (Lz= 6-pyridin-2-yl-[1, 3, 5] triazine-2, 4-diamine; …

An unsymmetrical coordination environment leading to two slow relaxation modes in a Dy 2 single-molecule magnet

PH Lin, WB Sun, MF Yu, GM Li, PF Yan… - Chemical …, 2011 - pubs.rsc.org
A Dy2 single-molecule magnet was isolated using a mixed ligand strategy in which the DyIII
ions adopt distinct coordination environments. This leads to two unique relaxation modes …