Magnetic Slow Relaxation in a Metal–Organic Framework Made of Chains of Ferromagnetically Coupled Single‐Molecule Magnets

G Huang, G Fernandez‐Garcia… - … A European Journal, 2018 - Wiley Online Library
We report the study of a Dy‐based metal–organic framework (MOF) with unprecedented
magnetic properties. The compound is made of nine‐coordinated DyIII magnetic building …

Systematic tuning of the magnetic properties in mixed-metal MOF-74

M Mukoyoshi, M Maesato, S Kawaguchi… - Inorganic …, 2022 - ACS Publications
Recently, mixed-metal metal–organic frameworks (MOFs) have been attracting much
attention in various fields. In this study, we have systematically investigated the magnetic …

Direct imaging of isolated single-molecule magnets in metal–organic frameworks

D Aulakh, L Liu, JR Varghese, H Xie… - Journal of the …, 2019 - ACS Publications
Practical applications involving the magnetic bistability of single-molecule magnets (SMMs)
for next-generation computer technologies require nanostructuring, organization, and …

Stable ferromagnetism and half-metallicity in two-dimensional polyporphyrin frameworks

J Tan, W Li, X He, M Zhao - Rsc Advances, 2013 - pubs.rsc.org
Two-dimensional (2D) organic materials with stable electron spin polarization, ferromagnetic
ordering and half-metallicity are quite promising for spintronics, due to their long spin …

Novel Co-based metal–organic frameworks and their magnetic properties using asymmetrically binding 4-(4′-carboxyphenyl)-1, 2, 4-triazole

T Aharen, F Habib, I Korobkov, TJ Burchell… - Dalton …, 2013 - pubs.rsc.org
Two novel Co-based metal–organic frameworks (MOFs) were synthesised and
characterised using an asymmetrically binding ligand, 4-(4′-carboxyphenyl)-1, 2, 4 triazole …

A three dimensional magnetically frustrated metal–organic framework via the vertices augmentation of underlying net

JP Zhao, SD Han, X Jiang, J Xu, Z Chang… - Chemical …, 2015 - pubs.rsc.org
In our efforts to fabricate magnetically frustrated materials, a feasible vertices augmentation
method was successfully used to construct a 4-fold interpenetrating three dimensional metal …

Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework

W Jiang, Z Liu, JW Mei, B Cui, F Liu - Nanoscale, 2019 - pubs.rsc.org
Dichotomy between local spins and conjugated electrons spawns various exotic physical
phenomena, however, it has mostly been reported in three-dimensional (3D) inorganic …

Construction of porous Mn (II)-based metal–organic frameworks by flexible hexacarboxylic acid and rigid coligands

FY Yi, S Dang, W Yang, ZM Sun - CrystEngComm, 2013 - pubs.rsc.org
Solvothermal reactions of hexa [4-(carboxyphenyl) oxamethyl]-3-oxapentane (H6L) with
rigid coligands, 2, 2′-bipyridine (bipy), 1, 4-bis-(1-imidazolyl) benzene (dib), and 4, 4′-bis …

Highly connected three-dimensional metal− organic frameworks based on polynuclear secondary building units

Z Su, SS Chen, J Fan, MS Chen, Y Zhao… - Crystal growth & …, 2010 - ACS Publications
A series of new highly connected MOFs [Cd (L)(PBEA) 0.5]· H2O (1),[Cd2 (μ3-
OH)(L)(PBEA)](2),[Cd3 (μ3-OH)(L) 2 (PBEA) 1.5]· H2O (3), and [Mn (μ2-H2O)(L)(PBEA) …

Single-molecule magnets within polyoxometalate-based frameworks

MB Zarch, M Mirzaei, M Bazargan, SK Gupta… - Dalton …, 2021 - pubs.rsc.org
As an extension of our interest in polyoxometalates (POMs) and lanthanoids, we report the
design and synthesis of two polyoxometalate-based frameworks under hydrothermal …