Synthetic Routes to the Cyclo[n]carbons

F Diederich, Y Rubin, OL Chapman… - Helvetica chimica …, 1994 - Wiley Online Library
Abstract Cyclo [n] carbons (cyclo‐Cn) are n‐membered monocyclic rings of sp‐hybridized C‐
atoms with unique electronic structures resulting from two perpendicular systems of …

Electronic Structure and Aromaticity of an Unusual Cyclo[18]carbon Precursor, C18Br6**

X Wang, Z Liu, J Wang, T Lu, W Xiong… - … A European Journal, 2023 - Wiley Online Library
Herein, the electronic structure and bonding character of the stable cyclo [18] carbon (C18)
precursor, C18Br6, are thoroughly characterized by molecular orbital (MO), density of states …

A New Entry into Cyclo[n]carbons:  [2 + 2] Cycloreversion of Propellane-Annelated Dehydroannulenes

Y Tobe, T Fujii, H Matsumoto, K Naemura… - Journal of the …, 1996 - ACS Publications
Increasing interest has been focused on cyclocarbons, the most stable form of carbon
clusters in the relatively narrow size range from C10 through C20. 1 Mechanistic studies on …

Towards the total synthesis of cyclo [n] carbons and the generation of cyclo [6] carbon

GA Adamson, CW Rees - Journal of the Chemical Society, Perkin …, 1996 - pubs.rsc.org
We describe efforts towards the synthesis of some allotropes of carbon, the cyclo [n] carbons
where n= 18, 24 and 30. The key intermediate 11 is hexa-1, 3, 5-triyne with the central triple …

[引用][C] Generation of Cyclocarbons with 4n Carbon Atoms (C12, C16, and C20) by [2 + 2] Cycloreversion of Propellane‐Annelated Dehydroannulenes

Y Tobe, H Matsumoto, K Naemura… - … Edition in English, 1996 - Wiley Online Library
The smallest C n clusters produced to date by [2+ 2] cycloreversion (cyclo‐C 12 and cyclo‐C
16) as well as cyclo‐C 20 can be synthesized from propellane‐annelated …

Synthesis of Cyclo[18]carbon via Debromination of C18Br6

LM Scriven, K Kaiser, F Schulz, AJ Sterling… - Journal of the …, 2020 - ACS Publications
Cyclo [18] carbon (C18, a molecular carbon allotrope) can be synthesized by
dehalogenation of a bromocyclocarbon precursor, C18Br6, in 64% yield, by atomic …

Precursors to the cyclo [n] carbons: from 3, 4-dialkynyl-3-cyclobutene-1, 2-diones and 3, 4-dialkynyl-3-cyclobutene-1, 2-diols to cyclobutenodehydroannulenes and …

Y Rubin, CB Knobler, F Diederich - Journal of the American …, 1990 - ACS Publications
A series of novel cyclobutenodehydro [n] annulenes (= 18, 24, 30) have been prepared as
precursors in an organic approach to the cyclocarbons C18, C24, and C30. On the way to …

Cyclacenes: hoop-shaped systems composed of conjugated rings

R Gleiter, B Esser, SC Kornmayer - Accounts of chemical …, 2009 - ACS Publications
A carbon nanotube, if it could be cut sideways at the end like a pipe, would yield beltlike
structures. These subunits of carbon nanotubes, in their simplest manifestation as the [6] n …

Potential molecular semiconductor devices: cyclo-C n (n= 10 and 14) with higher stabilities and aromaticities than acknowledged cyclo-C 18

M Li, Z Gao, Y Han, Y Zhao, K Yuan… - Physical Chemistry …, 2020 - pubs.rsc.org
The successful synthesis and isolation of cyclo-C18 in experiments is a ground-breaking
development in carbon rings. Herein, we studied the thermodynamic stabilities of cyclo-Cn …

Synthesis and properties of [9] cyclo-1, 4-naphthylene: a π-extended carbon nanoring

A Yagi, Y Segawa, K Itami - Journal of the American Chemical …, 2012 - ACS Publications
Synthesis and Properties of [9]Cyclo-1,4-naphthylene: A π-Extended Carbon Nanoring | Journal
of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log …