Covalently crosslinked polymeric materials, known as thermosets, possess enhanced
mechanical strength and thermal stability relative to the corresponding uncrosslinked …

With the goal to push the mechanical properties of reconfigurable supramolecular polymers
toward those of thermoset resins, we prepared and investigated a new family of hydrogen …

Thermoset elastomers have been extensively applied in many fields because of their
excellent mechanical strengths and durable characteristics, such as an excellent chemical …

Thermoset polymers with permanently cross-linked networks have outstanding mechanical
properties and solvent resistance, but they cannot be reprocessed or recycled. On the other …

Epoxies, epoxy acrylates, and acrylic resins account for a large portion of the thermoset
market, yet their inherently highly cross-linked nature prevents them from being reprocessed …

We demonstrated the modular synthesis of polymer thermosets exhibiting programmed
responses that arise from two predesigned functional units: a reversible cross-linker and a …

Topical application of diazirine-based crosslinkers can upgrade the mechanical properties
of low-functionality commodity plastics by engaging in rapid C–H insertions along the …

Vitrimers incorporating dioxaborolane covalent links are permanent polymeric networks that
combine the processability of thermoplastics with the thermomechanical and chemical …

Convenient strategies for the deconstruction and reprocessing of thermosets could improve
the circularity of these materials, but most approaches developed to date do not involve …

Thermosets—polymeric materials that adopt a permanent shape upon curing—have a key
role in the modern plastics and rubber industries, comprising about 20 per cent of polymeric …