Molecularly designed additives for chemically deconstructable thermosets without compromised thermomechanical properties
“Drop-in” additives that introduce chemically cleavable bonds into thermosets without
compromising thermomechanical properties could enable triggered material deconstruction …
compromising thermomechanical properties could enable triggered material deconstruction …
Thermally Crosslinked Functionalized Polydicyclopentadiene with a High Tg and Tunable Surface Energy
Polydicyclopentadiene (PDCPD) is a tough, heavily crosslinked thermoset polymer that has
high heat, chemical, and impact resistance coupled with a low density. Current limitations to …
high heat, chemical, and impact resistance coupled with a low density. Current limitations to …
Malleable and recyclable thermosets: The next generation of plastics
Malleable thermosets are crosslinked polymers containing dynamic covalent bonds, which
can be reversibly cleaved and reformed. They have attracted considerable attention in …
can be reversibly cleaved and reformed. They have attracted considerable attention in …
Efficient manufacture, deconstruction, and upcycling of high-performance thermosets and composites
Thermoset polymers and fiber-reinforced polymer composites possess the chemical,
physical, and mechanical properties necessary for energy-efficient vehicles and structures …
physical, and mechanical properties necessary for energy-efficient vehicles and structures …
Fully bio-based high-performance thermosets with closed-loop recyclability
K Hong, Q Sun, X Zhang, L Fan, T Wu… - ACS Sustainable …, 2022 - ACS Publications
Thermosets are important commodity polymeric materials, but they are rarely biorenewable
and recyclable. Although some previously reported bio-based aromatic thermosets with a …
and recyclable. Although some previously reported bio-based aromatic thermosets with a …
Catechol-modified epoxy backbones for multifunctional and ultra-tough thermoset
Y Shen, B Wang, D Li, W Yuan, Y Huang… - Chemical Engineering …, 2023 - Elsevier
Widely used traditional thermosets have drawn great attention due to their advantageous
features such as excellent stability, mechanical reliability etc. However, brittleness is still the …
features such as excellent stability, mechanical reliability etc. However, brittleness is still the …
Recent advances in recyclable thermosets and thermoset composites based on covalent adaptable networks
Y Zhang, L Zhang, G Yang, Y Yao, X Wei, T Pan… - Journal of Materials …, 2021 - Elsevier
Recyclable thermosets and thermoset composites with covalent adaptable networks (CANs,
or dynamic covalent networks) have attracted considerable attention in recent years due to …
or dynamic covalent networks) have attracted considerable attention in recent years due to …
Overcoming the entropy of polymer chains by making a plane with terminal groups: a thermoplastic PDMS with a long-range 1D structural order
Y Chen, F Ishiwari, T Fukui, T Kajitani, H Liu… - Chemical …, 2023 - pubs.rsc.org
Due to its unique physical and chemical properties, polydimethylsiloxane (PDMS) is widely
used in many applications, in which covalent cross-linking is commonly used to cure the …
used in many applications, in which covalent cross-linking is commonly used to cure the …
Recyclable and malleable thermosets enabled by activating dormant dynamic linkages
Chemical recycling of polymers is critical for improving the circular economy of plastics and
environmental sustainability. Traditional thermoset polymers have generally been …
environmental sustainability. Traditional thermoset polymers have generally been …
Dual cross-linked, polymer thermosets: modular design, reversible transformation, and triggered debonding
We demonstrated the modular synthesis of polymer thermosets exhibiting programmed
responses that arise from two predesigned functional units: a reversible cross-linker and a …
responses that arise from two predesigned functional units: a reversible cross-linker and a …