Molecularly designed additives for chemically deconstructable thermosets without compromised thermomechanical properties

KEL Husted, P Shieh, DJ Lundberg, SL Kristufek… - Acs Macro …, 2021 - ACS Publications
“Drop-in” additives that introduce chemically cleavable bonds into thermosets without
compromising thermomechanical properties could enable triggered material deconstruction …

Thermally Crosslinked Functionalized Polydicyclopentadiene with a High Tg and Tunable Surface Energy

J Chen, FP Burns, MG Moffitt, JE Wulff - ACS omega, 2016 - ACS Publications
Polydicyclopentadiene (PDCPD) is a tough, heavily crosslinked thermoset polymer that has
high heat, chemical, and impact resistance coupled with a low density. Current limitations to …

Malleable and recyclable thermosets: The next generation of plastics

Y Jin, Z Lei, P Taynton, S Huang, W Zhang - Matter, 2019 - cell.com
Malleable thermosets are crosslinked polymers containing dynamic covalent bonds, which
can be reversibly cleaved and reformed. They have attracted considerable attention in …

Efficient manufacture, deconstruction, and upcycling of high-performance thermosets and composites

EM Lloyd, JC Cooper, P Shieh, DG Ivanoff… - ACS Applied …, 2022 - ACS Publications
Thermoset polymers and fiber-reinforced polymer composites possess the chemical,
physical, and mechanical properties necessary for energy-efficient vehicles and structures …

Fully bio-based high-performance thermosets with closed-loop recyclability

K Hong, Q Sun, X Zhang, L Fan, T Wu… - ACS Sustainable …, 2022 - ACS Publications
Thermosets are important commodity polymeric materials, but they are rarely biorenewable
and recyclable. Although some previously reported bio-based aromatic thermosets with a …

Catechol-modified epoxy backbones for multifunctional and ultra-tough thermoset

Y Shen, B Wang, D Li, W Yuan, Y Huang… - Chemical Engineering …, 2023 - Elsevier
Widely used traditional thermosets have drawn great attention due to their advantageous
features such as excellent stability, mechanical reliability etc. However, brittleness is still the …

Recent advances in recyclable thermosets and thermoset composites based on covalent adaptable networks

Y Zhang, L Zhang, G Yang, Y Yao, X Wei, T Pan… - Journal of Materials …, 2021 - Elsevier
Recyclable thermosets and thermoset composites with covalent adaptable networks (CANs,
or dynamic covalent networks) have attracted considerable attention in recent years due to …

Overcoming the entropy of polymer chains by making a plane with terminal groups: a thermoplastic PDMS with a long-range 1D structural order

Y Chen, F Ishiwari, T Fukui, T Kajitani, H Liu… - Chemical …, 2023 - pubs.rsc.org
Due to its unique physical and chemical properties, polydimethylsiloxane (PDMS) is widely
used in many applications, in which covalent cross-linking is commonly used to cure the …

Recyclable and malleable thermosets enabled by activating dormant dynamic linkages

Z Lei, H Chen, C Luo, Y Rong, Y Hu, Y Jin, R Long… - Nature Chemistry, 2022 - nature.com
Chemical recycling of polymers is critical for improving the circular economy of plastics and
environmental sustainability. Traditional thermoset polymers have generally been …

Dual cross-linked, polymer thermosets: modular design, reversible transformation, and triggered debonding

Y Oh, J Park, JJ Park, S Jeong, H Kim - Chemistry of Materials, 2020 - ACS Publications
We demonstrated the modular synthesis of polymer thermosets exhibiting programmed
responses that arise from two predesigned functional units: a reversible cross-linker and a …