Conversion of amorphous calcium phosphate to microcrystalline hydroxyapatite. A pH-dependent, solution-mediated, solid-solid conversion

AL Boskey, AS Posner - The Journal of Physical Chemistry, 1973 - ACS Publications
The rate of formation of microcrystalline hydroxyapatite from amorphous calcium phosphate
has been studied at constant temperature as a function of the pH of the mediating solution; …

[引用][C] DIVISION OF BIOPHYSICS: KINETICS AND MECHANISM OF CONVERSION OF NONCRYSTALLINE CALCIUM PHOSPHATE TO CRYSTALLINE …

ED Eanes, AS Posner - Transactions of the New York Academy …, 1965 - Wiley Online Library
The noncrystalline phase was prepared by adding rapidly while stirring a 0.250 molar
solution of (NH4) 2HP04toa0. 750 molar solution of CaC12. 6H20, to achieve a final …

Calcium phosphate formation in vitro: II. Effects of environment on amorphous-crystalline transformation

JD Termine, RA Peckauskas, AS Posner - Archives of biochemistry and …, 1970 - Elsevier
The amount of time that actually elapsed during the solution mediated transformation of
amorphous calcium phosphate into crystalline apatite was short and invariable. On the other …

Growth of calcium phosphate on hydroxyapatite crystals. Effect of supersaturation and ionic medium

GH Nancollas, B Tomazic - The Journal of Physical Chemistry, 1974 - ACS Publications
The kinetics of growth of hydroxyapatite seed crystals has been studied at 25 and at
constantphysiological pH instable supersaturated solutions of calcium phosphate. The …

Formation of hydroxyapatite at low supersaturation

AL Boskey, AS Posner - The Journal of Physical Chemistry, 1976 - ACS Publications
The precipitation of hydroxyapatite, Caio (P04) 6 (OH) 2, from dilute solutions is discussed.
The degree of supersaturation of these dilute solutions (10s to 109, relative to …

Variations in solution chemistry during the low‐temperature formation of hydroxyapatite

PW Brown, N Hocker, S Hoyle - Journal of the American …, 1991 - Wiley Online Library
Both the kinetics and the microstructure of monolithic hydroxyapatite formed by a low‐
temperature dissolution and precipitation reaction strongly depend on the conditions in …

A thermodynamic analysis of the amorphous to crystalline calcium phosphate transformation

JL Meyer, ED Eanes - Calcified tissue research, 1978 - Springer
A thermodynamic analysis of the precipitation of amorphous calcium phosphate (ACP) and
its transformation to crystalline apatite has been made. A nearly constant ion product, over a …

A thermodynamic analysis of the secondary transition in the spontaneous precipitation of calcium phosphate

JL Meyer, ED Eanes - Calcified Tissue Research, 1978 - Springer
A thermodynamic analysis has been made of the secondary transition stage in the
spontaneous precipitation of calcium phosphate following the amorphous-crystalline …

The maturation of crystalline calcium phosphates in aqueous suspensions at physiologic pH

ED Eanes, JL Meyer - Calcified Tissue Research, 1977 - Springer
The maturation of calcium phosphate crystals formed by the conversion of spontaneously
precipitated amorphous calcium phosphate (ACP) was studied in aqueous media at …

Kinetics of hydroxyapatite formation at low temperature

PW Brown, M Fulmer - Journal of the American Ceramic …, 1991 - Wiley Online Library
The influence of temperature on the kinetics of formation of calcium‐deficient hydroxyapatite
by an acid‐base reaction has been determined. Calcium‐deficient hydroxyapatite is …