Alcohol-based Michaelis–Arbuzov reaction: an efficient and environmentally-benign method for C–P (O) bond formation

X Ma, Q Xu, H Li, C Su, L Yu, X Zhang, H Cao… - Green …, 2018 - pubs.rsc.org
The famous Michaelis–Arbuzov reaction is extensively used both in the laboratory and
industry to manufacture tons of widely-used organophosphoryl compounds every year …

Efficient one-pot synthesis of β-hydroxyphosphonates: regioselective nucleophilic ring opening reaction of epoxides with triethyl phosphite catalyzed by Al (OTf) 3

S Sobhani, A Vafaee - Tetrahedron, 2009 - Elsevier
A variety of β-hydroxyphosphonates were produced in high yields by ring opening reaction
of different types of epoxides with di/trialkyl phosphite esters catalyzed by Al (OTf) 3. The …

Reductive Coupling of P (O)–H Compounds and Aldehydes for the General Synthesis of Phosphines and Phosphine Oxides

J Wang, J Xiao, ZL Tang, DH Lan… - The Journal of Organic …, 2024 - ACS Publications
A novel strategy for the selective construction of a C (sp3)–P (III) or− P (V) bond from> P (O)–
H compounds and aldehydes is disclosed. By using the H3PO3/I2 system, various …

Copper-Catalyzed Phosphonation–Annulation Approaches to the Synthesis of β-Phosphonotetrahydrofurans Involving C–P and C–O Bonds Formation

Y Gao, X Li, W Chen, G Tang… - The Journal of Organic …, 2015 - ACS Publications
Substituted tetrahydrofuran derivatives play important roles as biological activities. A
versatile method for the synthesis of β-phosphonotetrahydrofurans has been developed …

Palladium‐Catalyzed Direct Decarbonylative Phosphorylation of Benzoic Acids with P (O)–H Compounds

JS Zhang, T Chen, LB Han - European Journal of Organic …, 2020 - Wiley Online Library
A direct decarbonylative phosphorylation of benzoic acids catalyzed by palladium was
disclosed. Under the reaction conditions, a wide range of benzoic acids coupled readily with …

Phosphaannulation by palladium-catalyzed carbonylation of C–H bonds of phosphonic and phosphinic acids

S Shin, Y Jeong, WH Jeon, PH Lee - Organic letters, 2014 - ACS Publications
An efficient phosphaannulation by Pd-catalyzed carbonylation of C–H bonds of phosphonic
and phosphinic acids for the synthesis of oxaphosphorinanone oxides is reported. These …

Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites

C Hou, Y Ren, R Lang, X Hu, C Xia, F Li - Chemical Communications, 2012 - pubs.rsc.org
The first Pd-catalyzed direct phosphonation of azoles with dialkyl phosphites has been
achieved without addition of base or acid. This method involves the oxidative cleavage of C …

Base-promoted O-deprotonation/alkylation reaction of P (O)–OH compounds with alkyl halides

B Xiong, Q Ye, X Feng, L Zhu, T Chen, Y Zhou, CT Au… - Tetrahedron, 2014 - Elsevier
A novel base-promoted O-deprotonation/alkylation reaction of P (O)–OH compounds with
alkyl halides has been developed. The protocol is practical, representing a simple way to …

P–C Bond formation via direct and three-component conjugate addition catalyzed by 1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene (TBD)

Z Jiang, Y Zhang, W Ye, CH Tan - Tetrahedron Letters, 2007 - Elsevier
The direct addition of P (O)–H bonds (dialkyl phosphites and diphenyl phosphonite) across
various activated alkenes was catalyzed effectively by 1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene …

Substituent-Controlled Chemoselective Cleavage of CC or Csp2–C(CO) Bond in α,β-Unsaturated Carbonyl Compounds with H-Phosphonates Leading to β …

Y Zhou, C Rao, S Mai, Q Song - The Journal of Organic Chemistry, 2016 - ACS Publications
An unprecedented substituent-controlled chemoselective cleavage of C C double bond or
C (sp2)–C (CO) bond along with aerobic phosphorylation of α, β-unsaturated carbonyl …