Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials

IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single-
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …

Rational design of single-molecule magnets: a supramolecular approach

T Glaser - Chemical communications, 2011 - pubs.rsc.org
Since the discovery that Mn121212OAc acts as a single-molecule magnet (SMM), an
increasing number of transition metal complexes have been demonstrated to behave as …

Organometallic single-molecule magnets

RA Layfield - Organometallics, 2014 - ACS Publications
Single-molecule magnets (SMMs) display slow relaxation of the magnetization, purely of
molecular origin, in the absence of an applied magnetic field. This review summarizes the …

Understanding the magnetic anisotropy toward single-ion magnets

YS Meng, SD Jiang, BW Wang… - Accounts of chemical …, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

JM Frost, KLM Harriman, M Murugesu - Chemical science, 2016 - pubs.rsc.org
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

A promising new route towards single-molecule magnets based on the oxalate ligand

GF Xu, QL Wang, P Gamez, Y Ma, R Clérac… - Chemical …, 2010 - pubs.rsc.org
A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge
has been designed through a rational synthetic approach. This strategy opens up new …

3d single-ion magnets

GA Craig, M Murrie - Chemical Society Reviews, 2015 - pubs.rsc.org
One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior

VV Novikov, AA Pavlov, YV Nelyubina… - Journal of the …, 2015 - ACS Publications
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …

A toolbox of building blocks, linkers and crystallisation methods used to generate single-chain magnets

S Dhers, HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets (SMMs) and single-chain magnets (SCMs) are potential
candidates for more dense data storage and quantum computing as well as providing …