Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials
IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single-
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …
Rational design of single-molecule magnets: a supramolecular approach
T Glaser - Chemical communications, 2011 - pubs.rsc.org
Since the discovery that Mn121212OAc acts as a single-molecule magnet (SMM), an
increasing number of transition metal complexes have been demonstrated to behave as …
increasing number of transition metal complexes have been demonstrated to behave as …
Organometallic single-molecule magnets
RA Layfield - Organometallics, 2014 - ACS Publications
Single-molecule magnets (SMMs) display slow relaxation of the magnetization, purely of
molecular origin, in the absence of an applied magnetic field. This review summarizes the …
molecular origin, in the absence of an applied magnetic field. This review summarizes the …
Understanding the magnetic anisotropy toward single-ion magnets
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …
preferentially after removal of the magnetic field below a certain temperature. The unique …
The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …
A promising new route towards single-molecule magnets based on the oxalate ligand
GF Xu, QL Wang, P Gamez, Y Ma, R Clérac… - Chemical …, 2010 - pubs.rsc.org
A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge
has been designed through a rational synthetic approach. This strategy opens up new …
has been designed through a rational synthetic approach. This strategy opens up new …
A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
A toolbox of building blocks, linkers and crystallisation methods used to generate single-chain magnets
S Dhers, HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets (SMMs) and single-chain magnets (SCMs) are potential
candidates for more dense data storage and quantum computing as well as providing …
candidates for more dense data storage and quantum computing as well as providing …