From colloidal nanoparticles to a single crystal: New insights into the formation of nacre's aragonite tablets

G Zhang, J Xu - Journal of structural biology, 2013 - Elsevier
Nacre has long served as a model for understanding the biomineralization mechanism and
designing bio-inspired materials. However, its basic building blocks, the aragonite tablets …

Unveiling the formation mechanism of pseudo-single-crystal aragonite platelets in nacre

X Li, Z Huang - Physical review letters, 2009 - APS
We demonstrate direct evidence that a single-crystal-like aragonite platelet is essentially
assembled with aragonite nanoparticles. The aragonite nanoparticles are readily oriented …

Order-disorder transition of aragonite nanoparticles in nacre

Z Huang, X Li - Physical Review Letters, 2012 - APS
Understanding nacre's bottom-up biomineralization mechanism, particularly, how individual
aragonite platelets are formed, has long remained elusive due to its crystallographic …

Transformation of ACC into aragonite and the origin of the nanogranular structure of nacre

E Macías-Sánchez, MG Willinger, CM Pina… - Scientific reports, 2017 - nature.com
Currently a basic tenet in biomineralization is that biominerals grow by accretion of
amorphous particles, which are later transformed into the corresponding mineral phase. The …

In vitro growth of nacre-like tablet forming: from amorphous calcium carbonate, nanostacks to hexagonal tablets

L Qiao, Q Feng, S Lu - Crystal Growth and Design, 2008 - ACS Publications
The structure and formation mechanism of nacre are hot research topics in
biomineralization. However, there is no specific conclusion about them. Especially for …

Unique morphology and gradient arrangement of nacre's platelets in green mussel shells

J Xu, G Zhang - Materials Science and Engineering: C, 2015 - Elsevier
Nacre has long served as a classic model in biomineralization and the synthesis of
biomimetic materials. However, the morphology and arrangement of its basic building …

Nanoscale transforming mineral phases in fresh nacre

RT DeVol, CY Sun, MA Marcus… - Journal of the …, 2015 - ACS Publications
Nacre, or mother-of-pearl, the iridescent inner layer of many mollusk shells, is a biomineral
lamellar composite of aragonite (CaCO3) and organic sheets. Biomineralization frequently …

[HTML][HTML] Earthworm granules: A model of non-classical biogenic calcium carbonate phase transformations

S Mandera, I Coronado, L Fernández-Díaz, M Mazur… - Acta biomaterialia, 2023 - Elsevier
Different non-classical crystallization mechanisms have been invoked to explain structural
and compositional properties of biocrystals. The identification of precursor amorphous …

Gradual ordering in red abalone nacre

P Gilbert, RA Metzler, D Zhou, A Scholl… - Journal of the …, 2008 - ACS Publications
Red abalone (Haliotis rufescens) nacre is a layered composite biomineral that contains
crystalline aragonite tablets confined by organic layers. Nacre is intensely studied because …

Nanoscale Analysis of the Structure and Composition of Biogenic Calcite Reveals the Biomineral Growth Pattern

M de Frutos, AB Rodríguez-Navarro, X Li, AG Checa - ACS nano, 2023 - ACS Publications
The vast majority of calcium carbonate biocrystals differ from inorganic crystals in that they
display a patent nanoroughness consisting of lumps of crystalline material …