[HTML][HTML] Thiol-and disulfide-based stimulus-responsive soft materials and self-assembling systems

DM Beaupre, RG Weiss - Molecules, 2021 - mdpi.com
Properties and applications of synthetic thiol-and disulfide-based materials, principally
polymers, are reviewed. Emphasis is placed on soft and self-assembling materials in which …

Thiolactone chemistry, a versatile platform for macromolecular engineering

N Illy, E Mongkhoun - Polymer Chemistry, 2022 - pubs.rsc.org
Thiolactones are often described as latent thiols. They can be ring-opened by hydroxy or
amine groups releasing thiols, which can further react with a large variety of functional …

[HTML][HTML] Closed-loop recycling of sulfur-rich polymers with tunable properties spanning thermoplastics, elastomers, and vitrimers

JZ Zhao, TJ Yue, BH Ren, XB Lu, WM Ren - Nature Communications, 2024 - nature.com
The development of closed-loop recycling polymers that exhibit excellent performance is of
great significance. Sulfur-rich polymers possessing excellent optical, thermal, and …

Poly (disulfide) s

EK Bang, M Lista, G Sforazzini, N Sakai, S Matile - Chemical Science, 2012 - pubs.rsc.org
Don't forget poly (disulfide) s. There is a rich literature pointing out the advantages of the
dynamic nature of single disulfide bridges to explore self-sorting, biomolecular engineering …

Dual‐Responsive Material Based on Catechol‐Modified Self‐Immolative Poly (Disulfide) Backbones

AH Agergaard, A Sommerfeldt… - Angewandte Chemie …, 2021 - Wiley Online Library
Functional materials engineered to degrade upon triggering are in high demand due their
potentially lower impact on the environment as well as their use in sensing and in medical …

Catalyst-free thiol–yne click polymerization: a powerful and facile tool for preparation of functional poly (vinylene sulfide) s

B Yao, J Mei, J Li, J Wang, H Wu, JZ Sun, A Qin… - …, 2014 - ACS Publications
The “thio-click” polymerization is a well-expanded concept of click polymerization. Among
the click polymerizations, the thiol–yne click polymerization is less developed and still in its …

Redox-responsive nanogels for drug-delivery: thiol–maleimide and thiol–disulfide exchange chemistry as orthogonal tools for fabrication and degradation

I Altinbasak, S Kocak, R Sanyal, A Sanyal - Polymer Chemistry, 2023 - pubs.rsc.org
Stimuli-responsive, readily functionalizable, and degradable nanogels have great potential
in targeted drug delivery applications. While crosslinked polymeric nanoparticles such as …

[HTML][HTML] Synthesis of unsymmetrical sulfamides and polysulfamides via SuFEx click chemistry

RW Kulow, JW Wu, C Kim, Q Michaudel - Chemical Science, 2020 - pubs.rsc.org
As hydrogen-bond donors and acceptors, N, N′-disubstituted sulfamides have been used
in a range of applications from medicinal chemistry to anion-binding catalysis. However …

Pyridyl disulfide reaction chemistry: an efficient strategy toward redox-responsive cyclic peptide–polymer conjugates

Q Song, J Yang, SCL Hall, P Gurnani… - ACS Macro …, 2019 - ACS Publications
Cyclic peptide–polymer conjugates are capable of self-assembling into supramolecular
polymeric nanotubes driven by the strong multiple hydrogen bonding interactions between …

Precise synthesis of poly (thioester) s with diverse structures by copolymerization of cyclic thioanhydrides and episulfides mediated by organic ammonium salts

TJ Yue, MC Zhang, GG Gu, LY Wang… - Angewandte …, 2019 - Wiley Online Library
The precise synthesis of poly (thioester) s with diverse structures is still a significant
challenge in the polymeric materials field. Herein, we report a novel approach to the …