Cyano‐Bridged MnIIIMIII Single‐Chain Magnets with MIII=CoIII, FeIII, MnIII, and CrIII

H Miyasaka, T Madanbashi, A Saitoh… - … A European Journal, 2012 - Wiley Online Library
A series of isostructural cyano‐bridged MnIII (hs)–MIII (ls) alternating chains,[MnIII (5‐
TMAMsalen) MIII (CN) 6]⋅ 4H2O (5‐TMAMsalen2−= N, N′‐ethylenebis (5 …

Single-Molecule Magnet Behavior in Heterometallic MII−MnIII2−MII Tetramers (MII = Cu, Ni) Containing MnIII Salen-Type Dinuclear Core

C Kachi-Terajima, H Miyasaka, A Saitoh… - Inorganic …, 2007 - ACS Publications
The linear-type heterometallic tetramers,[MnIII2 (5-MeOsaltmen) 2MII2 (L) 2](CF3SO3) 2⊙
2H2O (MII= Cu, 1a; Ni, 2a), where 5-MeOsaltmen2-= N, N '-(1, 1, 2, 2-tetramethylethylene) …

Raising the Spin-Reversal Barrier in Cyano-Bridged Single-Molecule Magnets: Linear MnIII2MIII(CN)6 (M = Cr, Fe) Species Incorporating [(5-Brsalen)Mn]+ Units

HJ Choi, JJ Sokol, JR Long - Inorganic chemistry, 2004 - ACS Publications
Reactions between K3 [M (CN) 6] and [Mn (5-Brsalen)(H2O) 2]+(5-Brsalen= N, N '-
ethylenebis (5-bromosalicylidene) aminato dianion) in a mixture of methanol and water …

Spin crossover in the cyanide-bridged Mo V Mn III single-chain magnet containing Fe II cations

JH Yoon, DW Ryu, SY Choi, HC Kim, EK Koh… - Chemical …, 2011 - pubs.rsc.org
A 1D MoVMnIII chain compound balanced by {Fe [HC (3, 5-Me2pz) 3] 2} 2+ dications was
prepared. This complex displays a typical single-chain magnet character associated with the …

Cyanide-Bridged Fe (III)− Mn (III) Chain with Metamagnetic Properties and Significant Magnetic Anisotropy

S Wang, M Ferbinteanu, M Yamashita - Inorganic chemistry, 2007 - ACS Publications
The assembling of [Mn (5-MeOsalen)(H2O)]+ and [(Tp) Fe (CN) 3]-affords the one-
dimensional zigzag chain [(Tp) Fe (CN) 3Mn (5-MeOsalen)⊙ 2CH3OH] n [1; Tp-= hydrotris …

Evidence for Single-Chain Magnet Behavior in a MnIII−NiII Chain Designed with High Spin Magnetic Units:  A Route to High Temperature Metastable Magnets

R Clérac, H Miyasaka, M Yamashita… - Journal of the American …, 2002 - ACS Publications
We herein present the synthesis, crystal structure, and magnetic properties of a new
heterometallic chain of MnIII and NiII ions,[Mn2 (saltmen) 2Ni (pao) 2 (py) 2](ClO4) 2 …

Cyano-bridged Fe (II)–Cr (III) single-chain magnet based on pentagonal bipyramid units: On the added value of aligned axial anisotropy

C Pichon, N Suaud, C Duhayon… - Journal of the …, 2018 - ACS Publications
A cyano-bridged Fe (II)–Cr (III) single-chain magnet designed to ensure a parallel
orientation of the axial anisotropy of the building units is reported. This ferromagnetic chain …

Synthesis, Structure, and Magnetic Properties of Three 1D Chain Complexes Based on High-Spin Metal–Cyanide Clusters: [MnIII6MIII] (M = Cr, Fe, Co)

HB Zhou, J Wang, HS Wang, YL Xu, XJ Song… - Inorganic …, 2011 - ACS Publications
On the basis of high-spin metal–cyanide clusters of MnIII6MIII (M= Cr, Fe, Co), three one-
dimensional (1D) chain complexes,[Mn (salen)] 6 [Cr (CN) 6] 2· 6CH3OH· H2O (1),[Mn (5 …

Cyano-Bridged MnIII3MIII (MIII = Fe, Cr) Complexes:  Synthesis, Structure, and Magnetic Properties

H Miyasaka, H Takahashi, T Madanbashi… - Inorganic …, 2005 - ACS Publications
Two cyano-bridged tetranuclear complexes composed of Mn (III) salen (salen= N, N '-
ethylene bis (salicylideneiminate)) and hexacyanometalate (III)(M= Fe, Cr) in a stoichiometry …

Direct evidence of exchange interaction dependence of magnetization relaxation in a family of ferromagnetic-type single-chain magnets

A Saitoh, H Miyasaka, M Yamashita… - Journal of Materials …, 2007 - pubs.rsc.org
Three Mn2Ni chains having the same repeating motif,[–MnIII–ON–NiII–NO–MnIII–(OPh) 2–]
n, possessing a structural C2 axis on the NiII ion and an inversion center at the midpoint of …