A Tetranuclear 3d−4f Single Molecule Magnet:  [CuIILTbIII(hfac)2]2

S Osa, T Kido, N Matsumoto, N Re… - Journal of the …, 2004 - ACS Publications
We report now the first single molecule magnet (SMM) consisting of d− f elements. The
present study demonstrates that the synthesis of the d− f polynuclear molecule is a very …

Significant enhancement of energy barriers in dinuclear dysprosium single-molecule magnets through electron-withdrawing effects

F Habib, G Brunet, V Vieru, I Korobkov… - Journal of the …, 2013 - ACS Publications
The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule
Magnets (SMMs) is investigated. By introducing highly electron-withdrawing atoms on …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Radical‐Bridged Heterometallic Single‐Molecule Magnets Incorporating Four Lanthanoceniums

P Zhang, QC Luo, Z Zhu, W He, N Song… - Angewandte …, 2023 - Wiley Online Library
The syntheses and magnetic properties of organometallic heterometallic compounds [K
(THF) 6]{CoI [(μ3‐HAN) RE2Cp* 4] 2}(1‐RE) and [K (Crypt)] 2 {CoI [(μ3‐HAN) RE2Cp* 4] …

Mn III\hfill\atop2\hfill (5‐Rsaltmen) 2NiII (pao) 2 (L) 2+: An ST= 3 Building Block for a Single‐Chain Magnet That Behaves as a Single‐Molecule Magnet

H Miyasaka, T Nezu, K Sugimoto… - … A European Journal, 2005 - Wiley Online Library
Abstract MnIII‐NiII‐MnIII linear‐type trinuclear complexes bridged by oximate groups were
selectively synthesized by the assembly reaction of Mn2 (5‐Rsaltmen) 2 (H2O) 2 (ClO4) 2 (5 …

Cyanometallate-bridged didysprosium single-molecule magnets constructed with single-ion magnet building block

Y Liu, YC Chen, J Liu, WB Chen, GZ Huang… - Inorganic …, 2019 - ACS Publications
The combination of magnetic interaction with high magnetic anisotropy provides a promising
way for modulating/fine-tuning molecular magnetic behaviors. Here, we show the building …

Lanthanide (III)-based single-ion magnets

A Dey, P Kalita, V Chandrasekhar - ACS omega, 2018 - ACS Publications
Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the
discovery of SIM properties in a bis-(phthalocyaninato) lanthanide complex. A recent report …

Cyclopentadienyl ligands in lanthanide single-molecule magnets: one ring to rule them all?

BM Day, FS Guo, RA Layfield - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The discovery of materials capable of storing magnetic information at the level
of single molecules and even single atoms has fueled renewed interest in the slow magnetic …

Enriching lanthanide single-ion magnetism through symmetry and axiality

SK Gupta, R Murugavel - Chemical Communications, 2018 - pubs.rsc.org
Rapidly growing modern information technology demands energy and cost efficient tools
that can efficiently store and process a large amount of data. However, the miniaturization …

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

VS Parmar, DP Mills… - Chemistry–A European …, 2021 - Wiley Online Library
Recent studies have shown that mononuclear lanthanide (Ln) complexes can be high‐
performing single‐molecule magnets (SMMs). Recently, there has been an influx of …