[PDF][PDF] A {Cr III 2 Dy III 2} single-molecule magnet: enhancing the blocking temperature through 3d magnetic exchange

SK Langley, DP Wielechowski, V Vieru, NF Chilton… - Angew …, 2013 - academia.edu
Single-molecule magnets (SMMs) are a fascinating class of molecular materials that display
slow relaxation of magnetization because of an intrinsic energy barrier (Ueff) to spin …

Controlled association of single-molecule magnets (SMMs) into coordination networks: towards a new generation of magnetic materials

IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single-
molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets

JD Rinehart, JR Long - Chemical Science, 2011 - pubs.rsc.org
Scientists have long employed lanthanide elements in the design of materials with
extraordinary magnetic properties, including the strongest magnets known, SmCo5 and …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

[HTML][HTML] Electro-activity and magnetic switching in lanthanide-based single-molecule magnets

O Cador, B Le Guennic, F Pointillart - Inorganic Chemistry Frontiers, 2019 - pubs.rsc.org
The control of the single-molecule magnet (SMM) behaviour is highly challenging but crucial
to design molecular materials suitable for potential applications in molecular devices. To …

A look at molecular nanosized magnets from the aspect of inter-molecular interactions

H Miyasaka, M Yamashita - Dalton Transactions, 2007 - pubs.rsc.org
Nanosized molecular magnetic materials such as single-molecule magnets and single-
chain magnets are recent attractive research targets in the fields of materials chemistry and …

[HTML][HTML] 3d single-ion magnets

GA Craig, M Murrie - Chemical Society Reviews, 2015 - pubs.rsc.org
One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

A high anisotropy barrier in a sulfur‐bridged organodysprosium single‐molecule magnet

F Tuna, CA Smith, M Bodensteiner, L Ungur… - Angewandte …, 2012 - Wiley Online Library
Following the discovery in the early 1990s that individual molecules can exhibit slow
relaxation of magnetization and magnetic hysteresis,[1] studies of single-molecule magnets …

[HTML][HTML] A monometallic lanthanide bis (methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour

M Gregson, NF Chilton, AM Ariciu, F Tuna… - Chemical …, 2016 - pubs.rsc.org
We report a dysprosium (III) bis (methanediide) single molecule magnet (SMM) where
stabilisation of the highly magnetic states and suppression of mixing of opposite magnetic …

What do 3d-4f butterflies tell us?

Y Peng, AK Powell - Coordination Chemistry Reviews, 2021 - Elsevier
The most studied examples of 3d-4f based single molecule magnets (SMMs) and their
coordination cluster counterparts is that of the 3d-4f butterfly systems which provide a test …