Chemical imaging of single catalyst particles with scanning μ-XANES-CT and μ-XRF-CT

SWT Price, K Ignatyev, K Geraki, M Basham… - Physical Chemistry …, 2015 - pubs.rsc.org
The physicochemical state of a catalyst is a key factor in determining both activity and
selectivity; however these materials are often not structurally or compositionally …

Coherent X-ray imaging of CO-adsorption-induced structural changes in Pt nanoparticles: implications for catalysis

M Abuin, YY Kim, H Runge, S Kulkarni… - ACS Applied Nano …, 2019 - ACS Publications
Using coherent X-ray diffraction imaging (CXDI) as an in situ tool, we determined the shape
and strain state of a platinum nanoparticle with≈ 160 nm diameter supported by a strontium …

Atomic imaging of carbon-supported Pt, Pt/Co, and Ir@ Pt nanocatalysts by atom-probe tomography

T Li, PAJ Bagot, E Christian, BRC Theobald… - Acs …, 2014 - ACS Publications
Atom probe tomography (APT) has been used to characterize commercially prepared Pt,
Pt/Co alloy, and Ir@ Pt core–shell nanoparticles supported on high-surface-area carbon …

X-ray physico-chemical imaging during activation of cobalt-based Fischer–Tropsch synthesis catalysts

AM Beale, SDM Jacques… - … of the Royal …, 2018 - royalsocietypublishing.org
The imaging of catalysts and other functional materials under reaction conditions has
advanced significantly in recent years. The combination of the computed tomography (CT) …

Hard X‐ray Nanotomography of Catalytic Solids at Work

ID Gonzalez‐Jimenez, K Cats, T Davidian… - Angewandte …, 2012 - Wiley Online Library
Advances in microscopy such as a spatial resolution in the nanometer range combined with
higher chemical and morphological sensitivities have improved the imaging of functional …

Mapping metal catalysts using synchrotron computed microtomography (CMT) and micro-X-ray fluorescence (μXRF)

KW Jonesa, H Fengb, A Lanzirottic, D Mahajan - Topics in catalysis, 2005 - Springer
Abstract Gas-to-liquids (GTL) is a viable pathway to synthesize clean fuels from natural gas.
The continuing technological advances in natural gas conversion technology have led …

In situ characterization of the 5d density of states of Pt nanoparticles upon adsorption of CO

P Glatzel, J Singh, KO Kvashnina… - Journal of the …, 2010 - ACS Publications
An element-selective study of the occupied and unoccupied density of electronic states in Pt
nanoparticles was performed using hard X-ray resonant inelastic X-ray scattering (RIXS). An …

Hard X‐ray spectroscopic nano‐imaging of hierarchical functional materials at work

JC Andrews, BM Weckhuysen - ChemPhysChem, 2013 - Wiley Online Library
Heterogeneous catalysts often consist of an active metal (oxide) in close contact with a
support material and various promoter elements. Although macroscopic properties, such as …

Nanoscale chemical imaging of the reduction behavior of a single catalyst particle

E de Smit, I Swart, JF Creemer… - Angewandte …, 2009 - Wiley Online Library
When studying catalyst materials by in situ chemical microspectroscopy, a trade-off is found
between the spatial resolution and chemical information of the acquired images …

Quantitative energy-dispersive X-ray analysis of catalyst nanoparticles using a partial cross section approach

KE MacArthur, TJA Slater, SJ Haigh… - Microscopy and …, 2016 - academic.oup.com
The new generation of energy-dispersive X-ray (EDX) detectors with higher count rates than
ever before, paves the way for a new approach to quantitative elemental analysis in the …