Observation of an Organic− Inorganic Lattice Match during Biomimetic Growth of (001)-Oriented Calcite Crystals under Floating Sulfate Monolayers

S Kewalramani, K Kim, B Stripe, G Evmenenko… - Langmuir, 2008 - ACS Publications
Macromolecular layers rich in amino acids and with some sulfated polysaccharides appear
to control oriented calcite growth in living organisms. Calcite crystals nucleating under …

Orientation and morphology of calcite nucleated under floating monolayers: A magnesium-ion-enhanced nucleation study

B Stripe, A Uysal, P Dutta - Journal of crystal growth, 2011 - Elsevier
We have studied the biomimetic growth of calcium carbonate crystals under floating
monolayer templates, in the presence of Mg ions, using grazing incidence X-ray diffraction …

Effects of chitosan on the alignment, morphology and shape of calcite crystals nucleating under Langmuir monolayers

K Kim, A Uysal, S Kewalramani, B Stripe, P Dutta - CrystEngComm, 2009 - pubs.rsc.org
The growth of calcium carbonate crystals under Langmuir monolayers was investigated in
the presence of chitosan, a soluble derivative of chitin added to the subphase to better …

Hydrogels coupled with self-assembled monolayers: an in vitro matrix to study calcite biomineralization

H Li, LA Estroff - Journal of the American Chemical Society, 2007 - ACS Publications
This paper describes the control of the nucleation and growth of calcite crystals by a matrix
composed of an agarose hydrogel on top of a carboxylate-terminated self-assembled …

Control over the vertical growth of single calcitic crystals in biomineralized structures

S Lee, SG Lee, M Sim, D Kwak, JH Park… - Crystal growth & …, 2011 - ACS Publications
Acidic biomacromolecules frequently incorporate into biomineralized structures to control
the morphology and extent of crystal growth. The study of such processes has been …

Calcite shape modulation through the lattice mismatch between the self-assembled monolayer template and the nucleated crystal face

B Pokroy, J Aizenberg - CrystEngComm, 2007 - pubs.rsc.org
The shapes of biologically formed calcite crystals are extremely versatile. Numerous studies
have addressed the possible biological mechanism of crystal shape regulation. Synthetic …

Patterned crystallization of calcite in vivo and in vitro

J Aizenberg - Journal of Crystal Growth, 2000 - Elsevier
Biologically formed calcite crystals have unique, sculptured shapes that are believed to be
regulated locally by specific macromolecules and by directional flux of ions into the …

A chemical model for the cooperation of sulfates and carboxylates in calcite crystal nucleation: relevance to biomineralization

L Addadi, J Moradian, E Shay… - Proceedings of the …, 1987 - National Acad Sciences
Acidic matrix macromolecules involved in regulation of biological crystal growth often
contain aspartic acid-rich domains and covalently bound sulfated polysaccharides. We …

Effect of magnesium ions on oriented growth of calcite on carboxylic acid functionalized self-assembled monolayer

YJ Han, J Aizenberg - Journal of the American Chemical Society, 2003 - ACS Publications
The combined effect of templating and solution additives on calcite crystallization was
studied. Self-assembled monolayers of mercaptoundecanoic acid supported on silver, as …

Crystal engineering of inorganic materials at organized organic surfaces

S Mann, BR Heywood, S Rajam, JBA Walker - 1991 - ACS Publications
The nucleation and growth of the mineral, CaCO3, under compressed Langmuir monolayers
has been studied by optical and electron microscopy and electron diffraction. The structure …