Observation of an Organic− Inorganic Lattice Match during Biomimetic Growth of (001)-Oriented Calcite Crystals under Floating Sulfate Monolayers
S Kewalramani, K Kim, B Stripe, G Evmenenko… - Langmuir, 2008 - ACS Publications
Macromolecular layers rich in amino acids and with some sulfated polysaccharides appear
to control oriented calcite growth in living organisms. Calcite crystals nucleating under …
to control oriented calcite growth in living organisms. Calcite crystals nucleating under …
Orientation and morphology of calcite nucleated under floating monolayers: A magnesium-ion-enhanced nucleation study
B Stripe, A Uysal, P Dutta - Journal of crystal growth, 2011 - Elsevier
We have studied the biomimetic growth of calcium carbonate crystals under floating
monolayer templates, in the presence of Mg ions, using grazing incidence X-ray diffraction …
monolayer templates, in the presence of Mg ions, using grazing incidence X-ray diffraction …
Effects of chitosan on the alignment, morphology and shape of calcite crystals nucleating under Langmuir monolayers
K Kim, A Uysal, S Kewalramani, B Stripe, P Dutta - CrystEngComm, 2009 - pubs.rsc.org
The growth of calcium carbonate crystals under Langmuir monolayers was investigated in
the presence of chitosan, a soluble derivative of chitin added to the subphase to better …
the presence of chitosan, a soluble derivative of chitin added to the subphase to better …
Hydrogels coupled with self-assembled monolayers: an in vitro matrix to study calcite biomineralization
H Li, LA Estroff - Journal of the American Chemical Society, 2007 - ACS Publications
This paper describes the control of the nucleation and growth of calcite crystals by a matrix
composed of an agarose hydrogel on top of a carboxylate-terminated self-assembled …
composed of an agarose hydrogel on top of a carboxylate-terminated self-assembled …
Control over the vertical growth of single calcitic crystals in biomineralized structures
Acidic biomacromolecules frequently incorporate into biomineralized structures to control
the morphology and extent of crystal growth. The study of such processes has been …
the morphology and extent of crystal growth. The study of such processes has been …
Calcite shape modulation through the lattice mismatch between the self-assembled monolayer template and the nucleated crystal face
B Pokroy, J Aizenberg - CrystEngComm, 2007 - pubs.rsc.org
The shapes of biologically formed calcite crystals are extremely versatile. Numerous studies
have addressed the possible biological mechanism of crystal shape regulation. Synthetic …
have addressed the possible biological mechanism of crystal shape regulation. Synthetic …
Patterned crystallization of calcite in vivo and in vitro
J Aizenberg - Journal of Crystal Growth, 2000 - Elsevier
Biologically formed calcite crystals have unique, sculptured shapes that are believed to be
regulated locally by specific macromolecules and by directional flux of ions into the …
regulated locally by specific macromolecules and by directional flux of ions into the …
A chemical model for the cooperation of sulfates and carboxylates in calcite crystal nucleation: relevance to biomineralization
L Addadi, J Moradian, E Shay… - Proceedings of the …, 1987 - National Acad Sciences
Acidic matrix macromolecules involved in regulation of biological crystal growth often
contain aspartic acid-rich domains and covalently bound sulfated polysaccharides. We …
contain aspartic acid-rich domains and covalently bound sulfated polysaccharides. We …
Effect of magnesium ions on oriented growth of calcite on carboxylic acid functionalized self-assembled monolayer
YJ Han, J Aizenberg - Journal of the American Chemical Society, 2003 - ACS Publications
The combined effect of templating and solution additives on calcite crystallization was
studied. Self-assembled monolayers of mercaptoundecanoic acid supported on silver, as …
studied. Self-assembled monolayers of mercaptoundecanoic acid supported on silver, as …
Crystal engineering of inorganic materials at organized organic surfaces
S Mann, BR Heywood, S Rajam, JBA Walker - 1991 - ACS Publications
The nucleation and growth of the mineral, CaCO3, under compressed Langmuir monolayers
has been studied by optical and electron microscopy and electron diffraction. The structure …
has been studied by optical and electron microscopy and electron diffraction. The structure …
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