Self‐assembly of supramolecular polymers into tunable helical structures

HJ Kim, YB Lim, M Lee - Journal of Polymer Science Part A …, 2008 - Wiley Online Library
There is growing interest in the design of synthetic molecules that are able to self‐assemble
into a polymeric chain with compact helical conformations, which is analogous to the folded …

[HTML][HTML] Stimuli-responsive synthetic helical polymers

M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …

A modular synthetic platform for the construction of protein-based supramolecular polymers via coiled-coil self-assembly

JK Staples, KM Oshaben, WS Horne - Chemical Science, 2012 - pubs.rsc.org
Programmed biomolecular self-assembly is a powerful method for the construction of
designed supramolecular materials. Here, we show that branched∼ 8 kDa subunits …

Architecture-Controllable Single-Crystal Helical Self-assembly of Small-Molecule Disulfides with Dynamic Chirality

Q Zhang, R Toyoda, L Pfeifer… - Journal of the American …, 2023 - ACS Publications
Beyond the common supramolecular helical polymers in solutions, controlling single-crystal
helical self-assembly with precisely defined chirality and architectures has been …

Helical architectures from self-assembly of chiral polymers and block copolymers

RM Ho, YW Chiang, SC Lin, CK Chen - Progress in polymer science, 2011 - Elsevier
Self-assembly is a spontaneous association of molecules under equilibrium conditions into
stable, well-defined aggregates by secondary interactions (ie, non-covalent forces). In 1985 …

Reversible transformation between rings and coils in a dynamic hydrogen-bonded self-assembly

S Yagai, S Kubota, H Saito, K Unoike… - Journal of the …, 2009 - ACS Publications
Several proteins, such as tobacco mosaic virus coat protein and the β protein of the
bacteriophage λ, are known to exhibit unique dynamic self-organization processes involving …

Rigid Dimers Formed through Strong Interdigitated H‐Bonds Yield Compact 1D Supramolecular Helical Polymers

A Ciesielski, AR Stefankiewicz, F Hanke, M Persson… - Small, 2011 - Wiley Online Library
Hierarchical self‐assembly of small abiotic molecular modules interacting through
noncovalent forces is increasingly being used to generate functional structures and …

Template‐induced and molecular recognition directed hierarchical generation of supramolecular assemblies from molecular strands

V Berl, MJ Krische, I Huc, JM Lehn… - … –A European Journal, 2000 - Wiley Online Library
The linear oligo‐isophthalamide strand 1 undergoes a conformational reorganization upon
binding of a cyanuric acid template as effector to afford a helical disklike object possessing …

Programmable assembly of peptide amphiphile via noncovalent-to-covalent bond conversion

K Sato, W Ji, LC Palmer, B Weber… - Journal of the …, 2017 - ACS Publications
Controlling the number of monomers in a supramolecular polymer has been a great
challenge in programmable self-assembly of organic molecules. One approach has been to …

Noncovalent interactions in the asymmetric synthesis of rigid, conjugated helical structures

M Miyasaka, M Pink, S Rajca, A Rajca - Angewandte Chemie, 2009 - Wiley Online Library
Helical supramolecular architecture, such as helical foldamers, supramolecular helicates
and aggregates, helical molecules, macromolecules, and oligomers, is a fascinating topic of …