Vanillin‐Derived Thermally Reprocessable and Chemically Recyclable Schiff‐Base Epoxy Thermosets

S Subramaniyan, M Bergoglio… - Global …, 2023 - Wiley Online Library
The paradigm shift from traditional petroleum‐based non‐recyclable thermosets to biobased
repeatedly recyclable materials is required to move toward circular bioeconomy. Here, two …

Versatile levulinic acid-derived dynamic covalent thermosets enabled by in situ generated imine and multiple hydrogen bonds

Y Liu, Z Yu, G Lu, W Chen, Z Ye, Y He, Z Tang… - Chemical Engineering …, 2023 - Elsevier
Bio-based dynamic covalent thermosets have attracted extensive attention as they are
expected to break conventional thermosets' reliance on fossil resources and address the …

Imine-functionalized biomass-derived dynamic covalent thermosets enabled by heat-induced self-crosslinking and reversible structures

W Xie, S Huang, S Liu, J Zhao - Chemical Engineering Journal, 2021 - Elsevier
Recently, the development of bio-derived high-performance thermosets has been widely
studied owing to the shortage of raw materials from fossil resources and the ecological and …

Fire-safe fully bio-based Schiff base epoxy thermosets with excellent mechanical properties and adjustable degradability

Z Miao, C Peng, L Xia, H Xu, S He, C Chi… - ACS Applied Polymer …, 2023 - ACS Publications
Currently, because of the depletion of petroleum resources and pollution problems
associated with the use of petrochemicals, bio-based epoxy thermosets have received wide …

Review of intrinsically recyclable biobased epoxy thermosets enabled by dynamic chemical bonds

MA Rashid, W Liu, Y Wei, Q Jiang - Polymer-Plastics Technology …, 2022 - Taylor & Francis
Epoxy thermosets are usually dependent on fossil fuel-based resources, commonly
diglycidyl ether bisphenol A (DGEBA) type epoxy monomers. However, the majority of these …

Biomass-derived dynamic covalent epoxy thermoset with robust mechanical properties and facile malleability

XM Ding, L Chen, X Luo, FM He, YF Xiao… - Chinese Chemical …, 2022 - Elsevier
Biomass-derived dynamic covalent thermoset has been considered as a promising solution
to the high dependence on fossil resources and the difficulty in recyclability after curing of …

Recyclable and degradable Vinylogous urethane epoxy thermosets with tunable mechanical properties from Isosorbide and Vanillic acid

R Yang, W Li, R Mo, X Zhang - ACS Applied Polymer Materials, 2023 - ACS Publications
Conventional epoxy resins derived from unsustainable petroleum resources are
unrecyclable and nondegradable. Herein, we facilely synthesized biobased vinylogous …

Biobased tannic acid cross-linked epoxy thermosets with hierarchical molecular structure and tunable properties: damping, shape memory, and recyclability

X Feng, J Fan, A Li, G Li - ACS Sustainable Chemistry & …, 2019 - ACS Publications
Biomass derivative and recyclability are two major factors in developing sustainable epoxy
thermosets that cope with the global oil crisis and climate change. However, the major …

High-performance, command-degradable, antibacterial Schiff base epoxy thermosets: synthesis and properties

X Xu, S Ma, J Wu, J Yang, B Wang, S Wang… - Journal of Materials …, 2019 - pubs.rsc.org
Two diepoxides containing a two-benzene-ring-conjugated Schiff base when cured with an
aromatic diamine result in high-performance thermosets combining excellent controlled …

Reprocessable, chemically recyclable, and flame-retardant biobased epoxy vitrimers

PX Tian, YD Li, Y Weng, Z Hu, JB Zeng - European Polymer Journal, 2023 - Elsevier
Conventional epoxy thermosets exhibit outstanding mechanical performances, excellent
thermal and dimensional stabilities, and prominent resistances to chemical/solvent …