Fully bio-based high-performance thermosets with closed-loop recyclability
K Hong, Q Sun, X Zhang, L Fan, T Wu… - ACS Sustainable …, 2022 - ACS Publications
Thermosets are important commodity polymeric materials, but they are rarely biorenewable
and recyclable. Although some previously reported bio-based aromatic thermosets with a …
and recyclable. Although some previously reported bio-based aromatic thermosets with a …
Recycling of epoxy thermoset and composites via good solvent assisted and small molecules participated exchange reactions
Thermosetting polymers and composites are a class of high-performance materials with
significant industrial applications. However, recycling of thermosets and their filling matters …
significant industrial applications. However, recycling of thermosets and their filling matters …
Covalent Adaptable Networks through Dynamic N,S-Acetal Chemistry: Toward Recyclable CO2-Based Thermosets
Finding new chemistry platforms for easily recyclable polymers has become a key challenge
to face environmental concerns and the growing plastics demand. Here, we report a …
to face environmental concerns and the growing plastics demand. Here, we report a …
Combining associative and dissociative dynamic linkages in covalent adaptable networks from biobased 2, 5-furandicarboxaldehyde
Covalent adaptable networks (CAN) emerged as a recent class of polymers that combine
the most interesting advantages of thermosets and thermoplastics. In this frame, combining …
the most interesting advantages of thermosets and thermoplastics. In this frame, combining …
Degradable thermosets derived from an isosorbide/succinic anhydride monomer and glycerol
PA Wilbon, JL Swartz, NR Meltzer… - ACS Sustainable …, 2017 - ACS Publications
Isosorbide is a renewable chemical of considerable interest as a monomer and monomer
precursor due to its potential use in replacements for fossil-fuel derived polymers. In the …
precursor due to its potential use in replacements for fossil-fuel derived polymers. In the …
Dynamic remodeling of covalent networks via ring-opening metathesis polymerization
Reversible transformations in bulk polymers offer numerous possibilities for materials
remodeling and reprocessing. While reversible systems based on dynamic covalent …
remodeling and reprocessing. While reversible systems based on dynamic covalent …
Biobased, high-performance covalent adaptable networks from levulinic acid and amino acids
Y Liu, Z Yu, B Wang, X Xu, H Feng, P Li… - ACS Sustainable …, 2022 - ACS Publications
Covalent adaptable networks (CANs) endow thermosets with recyclability (reprocessability
and degradability) and are expected to address the issues of environmental pollution and …
and degradability) and are expected to address the issues of environmental pollution and …
Mismatched Supramolecular Interactions Facilitate the Reprocessing of Super‐Strong and Ultra‐Tough Thermoset Elastomers
L Wang, K Zhang, X Zhang, Y Tan, L Guo… - Advanced …, 2024 - Wiley Online Library
Thermoset elastomers have been extensively applied in many fields because of their
excellent mechanical strengths and durable characteristics, such as an excellent chemical …
excellent mechanical strengths and durable characteristics, such as an excellent chemical …
Mechanically strong, thermally stable, and reprocessable poly (dimethylsiloxane) elastomers enabled by dynamic silyl ether linkages
X Yan, L Bai, B Feng, J Zheng - European Polymer Journal, 2022 - Elsevier
Endowing thermosetting materials with reprocessability by incorporating dynamic covalent
bonds into the polymer networks is of great realistic significance. However, as most dynamic …
bonds into the polymer networks is of great realistic significance. However, as most dynamic …
Dynamic ablative networks: shapeable heat-shielding materials
Thermoset materials sacrifice recyclability and reshapeability for increased chemical and
mechanical robustness because of an immobilized, cross-linked polymeric matrix. The …
mechanical robustness because of an immobilized, cross-linked polymeric matrix. The …