Chromium sorption by phlogopite and biotite in acidic solutions at 25 C: Insights from X-ray photoelectron spectroscopy and electron microscopy

ES Ilton, DR Veblen - Geochimica et Cosmochimica Acta, 1994 - Elsevier
Large single crystals of biotite and near endmember phlogopite were reacted with acidic Cr
(VI)-and Cr (III)-bearing solutions, at 24–27° C and 1 atm. After reaction of the micas with Cr …

The catalytic effect of sodium and lithium ions on coupled sorption-reduction of chromate at the biotite edge-fluid interface

ES Ilton, DR Veblen, CO Moses, SP Raeburn - … et Cosmochimica Acta, 1997 - Elsevier
Large single crystals of biotite and near-endmember phlogopite were reacted with aqueous
solutions bearing 20 μM Cr (VI) and different concentrations of NaCl, LiCl, RbCl, CsCl …

[HTML][HTML] Using X-ray photoelectron spectroscopy to discriminate among different sorption sites of micas: with implications for heterogeneous reduction of chromate at …

ES Ilton, CO Moses, DR Veblen - Geochimica et Cosmochimica Acta, 2000 - Elsevier
This contribution uses Cr2p and 3p binding energies (BEs) determined by X-ray
photoelectron spectroscopy (XPS) to distinguish CrIII sorbed to different mica sorption sites …

Cr (III) solubility in aqueous fluids at high pressures and temperatures

A Watenphul, C Schmidt, S Jahn - Geochimica et Cosmochimica Acta, 2014 - Elsevier
Trivalent chromium is generally considered relatively insoluble in aqueous fluids and melts.
However, numerous counterexamples in nature indicate Cr (III) mobilization by aqueous …

Biotite surface chemistry as a function of aqueous fluid composition

AW Bray, LG Benning, S Bonneville… - … et Cosmochimica Acta, 2014 - Elsevier
The chemical composition and charge of the biotite near-surface, in contact with NaCl
bearing aqueous solutions at 25° C from pH 1 to 12, have been derived via zeta potential …

Heterogeneous reduction of Tc (VII) by Fe (II) at the solid–water interface

T Peretyazhko, JM Zachara, SM Heald, BH Jeon… - … et Cosmochimica Acta, 2008 - Elsevier
Experiments were performed herein to investigate the rates and products of heterogeneous
reduction of Tc (VII) by Fe (II) adsorbed to hematite and goethite, and by Fe (II) associated …

Adsorbed Cr (III) on chlorite, illite, and kaolinite: An X-ray photoelectron spectroscopic study

MH Koppelman, AB Emerson, JG Dillard - Clays and Clay Minerals, 1980 - Springer
The adsorption of Cr (IH) was studied at pH 1, 2, 3, 4, 6, 8, and 10 on chlorite and kaolinite
and at pH 1, 2, 3, and 6 on illite. The amount of chromium adsorbed on chlorite varied from …

Binding and transport of Cr (III) by clay minerals during the Great Oxidation Event

W Hao, N Chen, W Sun, K Mänd, K Kirsimäe… - Earth and Planetary …, 2022 - Elsevier
A spike in chromium (Cr) abundance above crustal background in iron formations post-
dating the Great Oxidation Event (ca. 2.5-2.3 billion years ago) has been suggested to reflect …

Interaction between aqueous chromium solutions and layer silicates

MF Brigatti, G Franchini, C Lugli, L Medici, L Poppi… - Applied …, 2000 - Elsevier
The interactions between Cr in aqueous solutions and phyllosilicates were studied to
determine:(a) the amount of Cr (VI) to Cr (III) reduction in aqueous solutions by Fe (II) …

Structure and oxidation state of hematite surfaces reacted with aqueous Fe (II) at acidic and neutral pH

JG Catalano, P Fenter, C Park, Z Zhang… - … et Cosmochimica Acta, 2010 - Elsevier
Structural changes and surface oxidation state were examined following the reaction of
hematite (001),(012), and (110) with aqueous Fe (II). X-ray reflectivity measurements …