Size-dependent thermal stability and optical properties of ultra-small nanodiamonds synthesized under high pressure

E Ekimov, AA Shiryaev, Y Grigoriev, A Averin… - Nanomaterials, 2022 - mdpi.com
Diamond properties down to the quantum-size region are still poorly understood. High-
pressure high-temperature (HPHT) synthesis from chloroadamantane molecules allows …

High-pressure synthesis and optical properties of nanodiamonds obtained from halogenated adamantanes

EA Ekimov, MV Kondrin, SG Lyapin… - Diamond and Related …, 2020 - Elsevier
Following our previous brief communication the carbonization of halogenated adamantanes
C 10 H 14 Br 2 and C 10 H 15 Cl under high pressure with the aim to produce …

Size and Purity Control of HPHT Nanodiamonds down to 1 nm

S Stehlik, M Varga, M Ledinsky, V Jirasek… - The Journal of …, 2015 - ACS Publications
High-pressure high-temperature (HPHT) nanodiamonds originate from grinding of diamond
microcrystals obtained by HPHT synthesis. Here we report on a simple two-step approach to …

High-pressure, high-temperature synthesis and doping of nanodiamonds

EA Ekimov, MV Kondrin - Semiconductors and semimetals, 2020 - Elsevier
The synthesis of diamonds from hydrocarbons at high static pressures, first performed by
Wentorf more than half a century ago, is becoming an extremely important technology for …

High‐pressure synthesis of nanodiamonds from adamantane: myth or reality?

EA Ekimov, OS Kudryavtsev, NE Mordvinova… - …, 2018 - Wiley Online Library
The high‐pressure and high‐temperature technique is the most promising for mass
production of ultra‐small diamond nanoparticles of perfect structure. In the present work, this …

Nanodiamond size from low-frequency acoustic Raman modes

A Vlk, M Ledinsky, A Shiryaev, E Ekimov… - The Journal of …, 2022 - ACS Publications
Bottom-up high-pressure, high-temperature (BU_HPHT) synthesis of nanodiamonds (NDs)
from organic precursors has recently enabled unprecedented control over the ND size down …

Size effects on surface chemistry and Raman spectra of Sub-5 nm oxidized high-pressure high-temperature and detonation nanodiamonds

S Stehlik, M Mermoux, B Schummer… - The Journal of …, 2021 - ACS Publications
Understanding materials with dimensions down to a few nanometers is of major importance
for fundamental science as well as prospective applications. Structural transformation and …

Raman spectra and bulk modulus of nanodiamond in a size interval of 2–5 nm

M Popov, V Churkin, A Kirichenko, V Denisov… - Nanoscale research …, 2017 - Springer
Abstract Nanodiamond in a 2–5-nm size interval (which is typical for an appearance of
quantum confinement effect) show Raman spectra composed of 3 bands at 1325, 1600, and …

Laser heating versus phonon confinement effect in the Raman spectra of diamond nanoparticles

M Chaigneau, G Picardi, HA Girard, JC Arnault… - Journal of Nanoparticle …, 2012 - Springer
Nanodiamond particles with typical diameters of 20 and 6 nm produced by high pressure
high temperature or detonation processes have been studied by micro-Raman …

Convergence in the evolution of nanodiamond Raman spectra with particle size: a theoretical investigation

W Li, S Irle, HA Witek - ACS nano, 2010 - ACS Publications
Structural characterization of nanodiamonds by vibrational spectroscopy requires
knowledge of the factors determining the spectra. Raman spectroscopy is widely used to …