Quantifying the degree of nanofiller dispersion by advanced thermal analysis: application to polyester nanocomposites prepared by various elaboration methods

HE Miltner, N Watzeels, AL Goffin… - Journal of Materials …, 2010 - pubs.rsc.org
An innovative thermal analysis methodology is applied for the characterization of poly (ε-
caprolactone)(PCL) nanocomposites containing layered silicates, needle-like sepiolite or …

Qualitative assessment of nanofiller dispersion in poly (ε-caprolactone) nanocomposites by mechanical testing, dynamic rheometry and advanced thermal analysis

HE Miltner, N Watzeels, C Block, NA Gotzen… - European polymer …, 2010 - Elsevier
A comprehensive overview of available methods for assessing nanofiller dispersion is
presented for a wide range of layered silicate-based poly (ε-caprolactone)(PCL) …

The effect of nano-sized filler particles on the crystalline-amorphous interphase and thermal properties in polyester nanocomposites

HE Miltner, N Watzeels, NA Gotzen, AL Goffin… - Polymer, 2012 - Elsevier
Poly (epsilon-caprolactone)(PCL) nanocomposites containing carbon nanotubes, layered
silicates, sepiolite or polyhedral oligomeric silsesquioxane (POSS) were characterized by …

Structure, thermal transitions and polymer dynamics in nanocomposites based on poly (ε-caprolactone) and nano-inclusions of 1-3D geometry

S Koutsoumpis, A Poulakis, P Klonos, S Kripotou… - Thermochimica …, 2018 - Elsevier
Polymer nanocomposites, PNCs, based on poly (ε-caprolactone)(PCL) and four fillers
differing in shape, namely spherical silica and Ag nanoparticles (3D, referring to the number …

Effect of processing conditions on the morphology and properties of polymer nanocomposites

M Modesti, S Besco, A Lorenzetti - Optimization of Polymer …, 2010 - Wiley Online Library
The processing of hybrid polymer nanocomposites has been accomplished by several
routes, including the in situ polymerization of monomer/filler mixtures, solution intercalation …

Polymer grafted nanoparticle composites with enhanced thermal and mechanical properties

JM Kubiak, B Li, M Suazo… - ACS Applied Materials & …, 2022 - ACS Publications
The distribution of filler particles within a polymer matrix nanocomposite has a profound
influence on the properties and processability of the material. While filler aggregation and …

Strategies for the synthesis of thermoplastic polymer nanocomposite materials with high inorganic filling fraction

S Ojha, A Dang, CM Hui, C Mahoney… - Langmuir, 2013 - ACS Publications
The governing parameters controlling the miscibility of particle additives within polymeric
host media are analyzed for the particular case of silica particle fillers embedded within a …

(Re) processing effects on linear low-density polyethylene/silica nanocomposites

A Dorigato, A Pegoretti - Journal of Polymer Research, 2013 - Springer
A linear low density polyethylene matrix was melt compounded with a given amount (2
vol.%) of both untreated (hydrophilic) and surface treated (hydrophobic) fumed silica …

Thermal analysis of polymer layered silicate nanocomposites: Identification of nanostructure development by DSC

F Shiravand, I Fraga, P Cortés, Y Calventus… - Journal of Thermal …, 2014 - Springer
It has been shown, for three different polymer layered silicate (PLS) nanocomposite systems,
how differential scanning calorimetry (DSC) can identify the different reactions of …

Importance of superior dispersion versus filler surface modification in producing robust polymer nanocomposites: The example of polypropylene/nanosilica hybrids

KA Iyer, JM Torkelson - Polymer, 2015 - Elsevier
With polymer nanocomposites, achieving highly effective dispersion of agglomerated
nanofiller and major or optimal property enhancements remain challenges. A commonly …