Organosilicone compounds in supercritical carbon dioxide

VE Sizov, VV Zefirov, MO Gallyamov, AM Muzafarov - Polymers, 2022 - mdpi.com
This review considers the key advantages of using supercritical carbon dioxide as a solvent
for systems with organosilicon compounds. Organosilicon polymeric materials synthesis as …

Organosilicon compounds in supercritical carbon dioxide: Synthesis, polymerization, modification, and production of new materials

MA Pigaleva, IV Elmanovich, MN Temnikov… - Polymer Science Series …, 2016 - Springer
The main promising opportunities for the advantageous combination of organosilicon
compounds and supercritical carbon dioxide both as a solvent and as a reagent in chemical …

Silicon‐organic hybrid polymers and composites prepared in supercritical carbon dioxide

JW Green, MJ Rubal, BM Osman… - Polymers for …, 2000 - Wiley Online Library
Silicon‐containing organic/inorganic composites were prepared from poly (styrene‐co‐allyl
alcohol)(PSAA) and soluble starch (SS) by infusing SiCl 4 into them using supercritical …

Polymer synthesis and processing using supercritical carbon dioxide

AI Cooper - Journal of Materials Chemistry, 2000 - pubs.rsc.org
Carbon dioxide is a clean and versatile solvent for the synthesis and processing of a range
of materials. This review focuses on recent advances in polymer synthesis and processing …

Siloxane/silane‐crosslinked systems from supercritical carbon dioxide: II. Pendant phenyl poly (carbosilane/siloxane) s

H Zhou, SR Venumbaka, JW Fitch… - Polymers for …, 2008 - Wiley Online Library
New silicone‐containing polymers with crosslinkable units have been synthesized by
hydrosilation polymerization in both toluene and supercritical carbon dioxide (70° C, 3000 …

Green synthesis of polymers using supercritical carbon dioxide

CD Wood, AI Cooper, JM DeSimone - Current Opinion in Solid State and …, 2004 - Elsevier
Supercritical carbon dioxide is the most extensively studied supercritical fluid (SCF) medium
for polymerization reactions and organic transformations. This can be attributed to a list of …

Micro- and Nanoporous Materials Developed Using Supercritical CO2 Novel Synthetic Methods for the Development of Micro- and Nanoporous Materials Toward …

SN Paisner, JM DeSimone - 2004 - ACS Publications
A number of different types of nanoporous materials for use in low dielectric constant
applications have been developed in recent years, including nanoporous silica, polyimides …

Synthesis of poly (arylate-siloxane) s in supercritical carbon dioxide

AI Stakhanov, EE Said-Galiev, BA Izmailov… - Polymer Science Series …, 2008 - Springer
Abstract The reaction between poly (4, 4′-isopropylidene-2, 2′-diphenylene (tere)
isophthalate) copolymer and 3-aminopropyltriethoxysilane was investigated in supercritical …

New poly(silanes‐siloxanes) via hydrosilation in supercritical CO2 and subsequent crosslinking

H Zhou, SR Venumbaka, JW Fitch Iii… - Macromolecular …, 2003 - Wiley Online Library
In order to obtain crosslinkable, low dielectric, low Tg materials, the hydrosilation
polymerization was carried out in supercritical carbon dioxide (SC CO2) using Karstedt's …

Supercritical carbon dioxide as a green solvent for polymer synthesis

CD Wood, B Tan, H Zhang, AI Cooper - Thermodynamics, Solubility and …, 2007 - Elsevier
Publisher Summary This chapter focuses on the application of supercritical carbon dioxide
(scCO 2) as a solvent for polymer synthesis. ScCO 2 is an inexpensive, nontoxic, and …