Modern palladium-catalyzed transformations involving C–H activation and subsequent annulation

RS Thombal, PYM Rubio, D Lee, D Maiti, YR Lee - ACS Catalysis, 2022 - ACS Publications
The metal-catalyzed “cascade C–H activation/annulation” is a highly promising approach to
the construction of aromatic and heteroaromatic compounds. In this context, Pd-complexes …

Ring Construction by Palladium(0)-Catalyzed C(sp3)–H Activation

O Baudoin - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus The catalytic activation and functionalization of unactivated C (sp3)–H bonds of
alkyl groups has undergone intense development in recent years. In particular, a variety of …

C–H hetero-functionalization of arenes through palladacyclopentane-type intermediates

L Cao, Y Hua, HG Cheng, Q Zhou - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Recent years have witnessed palladium-catalyzed C–H activation emerging as a versatile
strategy for the construction of valuable scaffolds. Palladacyclopentane-type intermediates …

Palladium (II)‐catalyzed C H activation/C C cross‐coupling reactions: versatility and practicality

X Chen, KM Engle, DH Wang… - Angewandte Chemie …, 2009 - Wiley Online Library
Pick your Pd partners: A number of catalytic systems have been developed for palladium‐
catalyzed C H activation/C C bond formation. Recent studies concerning the palladium …

Palladium-catalyzed ligand-directed C− H functionalization reactions

TW Lyons, MS Sanford - Chemical reviews, 2010 - ACS Publications
The development of methods for the direct conversion of carbonshydrogen bonds into
carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds …

Palladium-catalyzed transformations of alkyl C–H bonds

J He, M Wasa, KSL Chan, Q Shao, JQ Yu - Chemical Reviews, 2017 - ACS Publications
This Review summarizes the advancements in Pd-catalyzed C (sp3)–H activation via
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …

Cross‐Coupling of C(sp3)–H Bonds with Organometallic Reagents via Pd(II)/Pd(0) Catalysis

M Wasa, KM Engle, JQ Yu - Israel journal of chemistry, 2010 - Wiley Online Library
Palladium‐catalyzed C–H activation/C–C bond‐forming reactions have emerged as a
promising class of synthetic tools in organic chemistry. Among the many different means of …

Recent advances in palladium-catalyzed C (sp3)–H activation for the formation of carbon–carbon and carbon–heteroatom bonds

N Dastbaravardeh, M Christakakou, M Haider… - …, 2014 - thieme-connect.com
Within this review, recent developments in the field of C (sp 3)–H activation catalyzed by
palladium are discussed. Both intra-and intermolecular reactions towards carbon–carbon …

Recent developments in palladium-catalysed non-directed C–H bond activation in arenes

S Kancherla, KB Jørgensen, MÁ Fernández-Ibáñez - Synthesis, 2019 - thieme-connect.com
Over the past decades, organic chemists have focussed on developing new approaches to
directed C–H functionalisations, where the site selectivity is steered by the presence of a …

Direct Allylic Functionalization Through Pd‐Catalyzed C–H Activation

F Liron, J Oble, MM Lorion, G Poli - European Journal of …, 2014 - Wiley Online Library
After a brief introduction emphasizing the synthetic relevance of the allylic C–H activation
step, evoking the first pioneering stoichiometric studies that sowed the “seeds” of this …