Syntheses of quaternary ammonium-containing, trithiocarbonate RAFT agents and hemi-telechelic cationomers

L Zhang, LR Cool, C Wesdemiotis, RA Weiss… - Polymer …, 2014 - pubs.rsc.org
We reported herein a facile and high-yield approach to synthesize a series of
trithiocarbonate RAFT agents containing quaternary ammonium functionality in the “R …

Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents

JT Lai, D Filla, R Shea - Macromolecules, 2002 - ACS Publications
Introduction. Recent development of controlled radical polymerization leads to the synthesis
of many welldefined architectures with predictable molecular weights. The most important …

Synthesis and characterization of quaternary phosphonium-containing, trithiocarbonate RAFT agents

L Zhang, Q Tang, RA Weiss, KA Cavicchi - Polymer Chemistry, 2014 - pubs.rsc.org
In this article the syntheses of quaternary phosphonium-containing trithiocarbonate RAFT
agents (RAFT-PR3, R= Bu and Ph) and their use in the bulk, thermally initiated …

Carbazyl RAFT agents synthesized by an improved aqueous phase method and their applications in RAFT polymerization

J Zhang, A Dong, T Cao, R Guo - European polymer journal, 2008 - Elsevier
A series of carbazyl dithiocarbamates as RAFT agents, ie benzyl 9H-carbazole-9-
carbodithioate (B), 1-phenylethyl 9H-carbazole-9-carbodithioate (C), cumyl 9H-carbazole-9 …

One-pot Modular Synthesis of Functionalized RAFT agents derived from a single Thiolactone Precursor

S Martens, F Driessen, S Wallyn, O Türünç… - ACS Macro …, 2016 - ACS Publications
In this paper, the straightforward preparation of a range of functionalized trithiocarbonates as
RAFT chain transfer agents (CTAs) is presented. The crucial step in the one-pot, three-step …

Synthesis and Characterization of novel quaternary ammonium RAFT agents

A Samakande, RD Sanderson… - Synthetic …, 2007 - Taylor & Francis
Synthesis of three new cationic thio compounds suitable to control free‐radical
polymerization according to the reversible addition fragmentation chain transfer (RAFT) …

Synthesis and Evaluation of New Dicarboxylic Acid Functional Trithiocarbonates:  RAFT Synthesis of Telechelic Poly(n-butyl acrylate)s

R Wang, CL McCormick, AB Lowe - Macromolecules, 2005 - ACS Publications
We report herein the synthesis of three new diacid functional trithiocarbonates (TTCs) in
which the substitution pattern about the TTC functionality is varied and compare their …

Syntheses of benzhydryl 2-propanoyl-functionalized trithiocarbonates and its use as chain transfer agents in the RAFT polymerization of styrene

GJ Summers, TS Motsoeneng, CA Summers - European Polymer Journal, 2021 - Elsevier
The preparation of three new benzhydryl 2-propanoyl-functionalized trithiocarbonate RAFT
agents, benzhydryl 2-(ethylsulfanylthiocarbonylsulfanyl) propanoate, benzhydryl 2 …

Dithiocarbamate RAFT agents with broad applicability–the 3, 5-dimethyl-1 H-pyrazole-1-carbodithioates

J Gardiner, I Martinez-Botella, J Tsanaktsidis… - Polymer …, 2016 - pubs.rsc.org
3, 5-Dimethyl-1H-pyrazole-1-carbodithioates are shown to be extremely versatile
dithiocarbamate RAFT agents with wide-spread applicability. The cyanomethyl and benzyl …

[PDF][PDF] Vinylogous thionothio compounds for RAFT polymerization

M Destarac, I Gauthier-Gillaizeau, CT Vuong… - Macromolecules, 2006 - academia.edu
Introduction. In recent years, considerable attention has been paid to controlled/living radical
polymerization. 1 Reversible addition-fragmentation chain transfer (RAFT) polymerization is …