Reversible Addition Fragmentation chain Transfer (RAFT) polymerization with a polymeric RAFT agent containing multiple trithiocarbonate groups

Y Liu, KA Cavicchi - Macromolecular Chemistry and Physics, 2009 - Wiley Online Library
Polytrithiocarbonates were prepared by the condensation polymerization of a dicarboxylic
acid functional trithiocarbonate and a diol. These polymers were effective reversible addition …

Effect of scandium triflate on the RAFT copolymerization of methyl acrylate and vinyl acetate controlled by an acid/base “switchable” chain transfer agent

A Tselepy, TL Schiller, S Harrisson… - …, 2018 - ACS Publications
Modulation of the activity of an acid/base switchable dithiocarbamate RAFT agent,
cyanomethyl (4-fluorophenyl)(pyridin-4-yl) carbamodithioate, with the Lewis acid scandium …

Synthesis of well‐defined three‐armed polystyrene having thiourethane–isocyanurate as the core structure derived from trifunctional five‐membered cyclic …

A Suzuki, D Nagai, B Ochiai… - Journal of Polymer …, 2005 - Wiley Online Library
The synthesis of a three‐armed polymer with an isocyanurate–thiourethane core structure is
described. Monofunctional reversible addition–fragmentation chain transfer (RAFT) agent 2 …

Multiblock copolymers of styrene and butyl acrylate via polytrithiocarbonate-mediated RAFT polymerization

B Ebeling, P Vana - Polymers, 2011 - mdpi.com
When linear polytrithiocarbonates as Reversible Addition-Fragmentation chain Transfer
(RAFT) agents are employed in a radical polymerization, the resulting macromolecules …

Diversifying cationic RAFT polymerization with various counteranions: generation of cationic species from organic halides and various metal salts

M Uchiyama, K Satoh, M Kamigaito - Acs Macro Letters, 2016 - ACS Publications
A combination of hydrogen chloride adduct of isobutyl vinyl ether (IBVE–HCl) and various
metal salts (AgOTf, AgPF6, AgSbF6, NaBArF (BArF:[3, 5-(CF3) 2Ph] 4B)) efficiently …

RAFT Polymerization of Styrene in the Presence of 2‐Nonyl‐benzoimidazole‐1‐carbodithioic Acid Benzyl Ester

H Yin, Z Cheng, J Zhu, X Zhu - … Science, Part A: Pure and Applied …, 2007 - Taylor & Francis
A novel dithiocarbamate, 2‐nonyl‐benzoimidazole‐1‐carbodithioic acid benzyl ester (1a),
was synthesized and successfully used in RAFT polymerization of styrene in bulk with …

Synthesis and characterization of telechelic polymethacrylates via RAFT polymerization

V Lima, X Jiang, J Brokken‐Zijp… - Journal of Polymer …, 2005 - Wiley Online Library
The reversible addition–fragmentation chain transfer (RAFT) polymerization technique has
been employed to synthesize linear α, ω‐telechelic polymers with either hydroxyl or carboxyl …

Reversible addition–fragmentation chain transfer polymerizations of styrene with two novel trithiocarbonates as RAFT agents

J Fu, Z Cheng, N Zhou, J Zhu, W Zhang, X Zhu - Polymer, 2008 - Elsevier
Two novel reversible addition–fragmentation chain transfer (RAFT) reagents bearing
functional groups, S, S′-bis (9-anthrylmethyl) trithiocarbonate (BATTC) and S, S′-bis (1 …

Phosphinoyl and thiophosphinoylcarbodithioates: synthesis, molecular structure, and application as new efficient mediators for raft polymerization

S Mazières, I Kulai, R Geagea… - … A European Journal, 2015 - Wiley Online Library
New phosphinoyl and thiophosphinoylcarbodithioates were synthesized in a one‐pot
reaction from the corresponding phosphinochalcogenides. Compounds of this new …

The effect of Z-group modification on the RAFT polymerization of N-vinylpyrrolidone controlled by “switchable” N-pyridyl-functional dithiocarbamates

SJ Stace, G Moad, CM Fellows, DJ Keddie - Polymer Chemistry, 2015 - pubs.rsc.org
The ability of a RAFT agent to control the polymerization of a monomer is dictated by the
structures of both the monomer and the RAFT agent. In this paper, the polymerization of N …