[HTML][HTML] Field-induced single-ion magnet based on a quasi-octahedral Co (II) complex with mixed sulfur–oxygen coordination environment

DV Korchagin, YE Gureev, EA Yureva, GV Shilov… - Dalton …, 2021 - pubs.rsc.org
Synthesis and characterization of structure and magnetic properties of the quasi-octahedral
complex (pipH2)[Co (TDA) 2] 2H2O (I),(pipH22+= piperazine dication, TDA2−= thiodiacetic …

[HTML][HTML] A Series of Field-Induced Single-Ion Magnets Based on the Seven-Coordinate Co(II) Complexes with the Pentadentate (N3O2) H2dapsc Ligand

VA Kopotkov, DV Korchagin, VD Sasnovskaya… - Magnetochemistry, 2019 - mdpi.com
A series of five new mononuclear pentagonal bipyramidal Co (II) complexes with the
equatorial 2, 6-diacetylpyridine bis (semicarbazone) ligand (H2dapsc) and various axial …

Field-induced single-ion magnet behaviour of a hexacoordinated Co (II) complex with easy-axis-type magnetic anisotropy

YP Tupolova, IN Shcherbakov, LD Popov… - Dalton …, 2019 - pubs.rsc.org
A coordination compound with the composition [CoLCl2]· H2O (L= bis-condensation product
of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine) was synthesized, in which the Co (II) …

[HTML][HTML] Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co {(OPPh 2)(EPPh 2) N} 2], E= S, Se, explored by experimental and …

E Ferentinos, D Tzeli, S Sottini, EJJ Groenen… - Dalton …, 2023 - pubs.rsc.org
During the last few years, a large number of mononuclear Co (II) complexes of various
coordination geometries have been explored as potential single ion magnets (SIMs). In the …

Field-Induced Co(II) Single-Ion Magnets with mer-Directing Ligands but Ambiguous Coordination Geometry

Y Peng, V Mereacre, CE Anson, Y Zhang… - Inorganic …, 2017 - ACS Publications
Three air-stable Co (II) mononuclear complexes with different aromatic substituents have
been prepared and structurally characterized by single-crystal X-ray diffraction. The …

Fine-Tuning of Uniaxial Anisotropy and Slow Relaxation of Magnetization in the Hexacoordinate Co (II) Complexes with Acidoligands

YP Tupolova, IN Shcherbakov… - The Journal of …, 2020 - ACS Publications
A new hexacoordinate Co (II) complex with the general formula [CoL (NCS) 2]· DMSO (1)(L=
biscondensation product of diacetyl and 2-hydrazinyl-4, 6-dimethylpyrimidine, DMSO …

On balancing the QTM and the direct relaxation processes in single-ion magnets–the importance of symmetry control

YF Deng, T Han, B Yin, YZ Zheng - Inorganic Chemistry Frontiers, 2017 - pubs.rsc.org
Two mononuclear trigonal-planar Co (II) complexes [Na (THF) 6][Co (OAr) 3] 1 and [(THF)
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …

A family of related Co (II) terpyridine compounds exhibiting field induced single-molecule magnet properties

RF Higgins, BN Livesay, TJ Ozumerzifon, JP Joyce… - Polyhedron, 2018 - Elsevier
We describe the syntheses, crystal structures and magnetic properties of several Co (II)
complexes containing 4′-pyrrolidine-2, 2′: 6′, 2 ″-terpyridine (pyrtpy) or 4 …

Field-induced slow magnetic relaxation in pseudooctahedral cobalt (II) complexes with positive axial and large rhombic anisotropy

A Świtlicka, J Palion-Gazda, B Machura, J Cano… - Dalton …, 2019 - pubs.rsc.org
The preparation, X-ray crystal structure, spectroscopic and variable-temperature dc and ac
magnetic properties of two six-coordinate cobalt (II) complexes of formula [Co (bim) 4 (tcm) …

[HTML][HTML] Effect of linear and non-linear pseudohalides on the structural and magnetic properties of Co (II) hexacoordinate single-molecule magnets

L Váhovská, S Vitushkina, I Potočňák, Z Trávníček… - Dalton …, 2018 - pubs.rsc.org
A series of mononuclear hexacoordinate Co (II) complexes with the 4-amino-3, 5-bis (2-
pyridyl)-1, 2, 4-triazole (abpt) ligand and various linear and non-linear pseudohalides, such …