Direct structural evidence for interfacial gradients in asymmetric polymer nanocomposite blends
AC Genix, V Bocharova, B Carroll… - … Applied Materials & …, 2021 - ACS Publications
Understanding the complex structure of polymer blends filled with nanoparticles (NPs) is key
to design their macroscopic properties. Here, the spatial distribution of hydrogenated (H) …
to design their macroscopic properties. Here, the spatial distribution of hydrogenated (H) …
Effect of bidispersity in grafted chain length on grafted chain conformations and potential of mean force between polymer grafted nanoparticles in a homopolymer …
In efforts to produce polymeric materials with tailored physical properties, significant interest
has grown around the ability to control the spatial organization of nanoparticles in polymer …
has grown around the ability to control the spatial organization of nanoparticles in polymer …
Structure–property relationships of polymer-grafted nanospheres for designing advanced nanocomposites
Polymer-grafted nanoparticles are an important component of many classes of polymer
nanocomposites. Here, we review the structure of polymer brushes on spherical …
nanocomposites. Here, we review the structure of polymer brushes on spherical …
Investigation of the surface glass transition temperature by embedding of noble metal nanoclusters into monodisperse polystyrenes
J Erichsen, J Kanzow, U Schürmann, K Dolgner… - …, 2004 - ACS Publications
Chain mobility in a near surface region at a polystyrene/vacuum interface was investigated
by embedding of noble metal nanosized clusters. The embedding process was monitored in …
by embedding of noble metal nanosized clusters. The embedding process was monitored in …
Effect of nanoparticle dispersion on glass transition in thin films of polymer nanocomposites
S Chandran, JK Basu - The European Physical Journal E, 2011 - Springer
We present spectroscopic ellipsometry measurements on thin films of polymer
nanocomposites consisting of gold nanoparticles embedded in poly (styrene). The …
nanocomposites consisting of gold nanoparticles embedded in poly (styrene). The …
Entropy-driven segregation of polymer-grafted nanoparticles under confinement
R Zhang, B Lee, CM Stafford… - Proceedings of the …, 2017 - National Acad Sciences
The modification of nanoparticles with polymer ligands has emerged as a versatile approach
to control the interactions and organization of nanoparticles in polymer nanocomposite …
to control the interactions and organization of nanoparticles in polymer nanocomposite …
Wetting and chain packing across interfacial zones affect distribution of relaxations in polymer and polymer-grafted nanocomposites
Polymers exhibit deviations from their bulk physical properties in the vicinity of solid
interfaces due to changes in configurations, entanglements, and relaxation dynamics at the …
interfaces due to changes in configurations, entanglements, and relaxation dynamics at the …
Interphase structures and dynamics near nanofiller surfaces in polymer solutions
We report the in situ structures and dynamics of hydrogenated polybutadiene (PB) chains
bound to carbon black nanoparticle surfaces in polymer solutions composed of deuterated …
bound to carbon black nanoparticle surfaces in polymer solutions composed of deuterated …
Surface dynamics of miscible polymer blend nanocomposites
B Frieberg, J Kim, S Narayanan, PF Green - Acs Nano, 2014 - ACS Publications
Diverse processes that include energy conversion, wettability, lubrication, adhesion, and
surface-directed phase separation in mixtures fundamentally depend on the structure and …
surface-directed phase separation in mixtures fundamentally depend on the structure and …
Exchange lifetimes of the bound polymer layer on silica nanoparticles
Understanding the structure and dynamics of the bound polymer layer (BL) that forms on
favorably interacting nanoparticles (NPs) is critical to revealing the mechanisms responsible …
favorably interacting nanoparticles (NPs) is critical to revealing the mechanisms responsible …