Hydrogenases
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
A third type of hydrogenase catalyzing H2 activation
S Shima, RK Thauer - The chemical record, 2007 - Wiley Online Library
The activation of molecular hydrogen is of interest both from a chemical and biological
viewpoint. The covalent bond of H2 is strong (436 kJ mol− 1). Its cleavage is catalyzed by …
viewpoint. The covalent bond of H2 is strong (436 kJ mol− 1). Its cleavage is catalyzed by …
The hydrogen issue
N Armaroli, V Balzani - ChemSusChem, 2011 - Wiley Online Library
Hydrogen is often proposed as the fuel of the future, but the transformation from the present
fossil fuel economy to a hydrogen economy will need the solution of numerous complex …
fossil fuel economy to a hydrogen economy will need the solution of numerous complex …
Hydrogenases: hydrogen‐activating enzymes
M Frey - ChemBioChem, 2002 - Wiley Online Library
Many microorganisms, such as methanogenic, acetogenic, nitrogen-fixing, photosynthetic,
or sulfate-reducing bacteria, metabolize hydrogen.[1, 2a] Hydrogen activation is mediated by …
or sulfate-reducing bacteria, metabolize hydrogen.[1, 2a] Hydrogen activation is mediated by …
Structure/function relationships of [NiFe]-and [FeFe]-hydrogenases
JC Fontecilla-Camps, A Volbeda, C Cavazza… - Chemical …, 2007 - ACS Publications
The utilization of hydrogen by micro-organisms as a source of reducing power or of protons
as final electron acceptors is mediated by metalloenzymes called hydrogenases. The need …
as final electron acceptors is mediated by metalloenzymes called hydrogenases. The need …
The crystal structure of [Fe]-hydrogenase reveals the geometry of the active site
S Shima, O Pilak, S Vogt, M Schick, MS Stagni… - Science, 2008 - science.org
Biological formation and consumption of molecular hydrogen (H2) are catalyzed by
hydrogenases, of which three phylogenetically unrelated types are known:[NiFe] …
hydrogenases, of which three phylogenetically unrelated types are known:[NiFe] …
[图书][B] Introduction to hydrogen technology
KSV Santhanam, RJ Press, MJ Miri, AV Bailey… - 2017 - books.google.com
Introduces the field of hydrogen technology and explains the basic chemistry underlying
promising and innovative new technologies This new and completely updated edition of …
promising and innovative new technologies This new and completely updated edition of …
[图书][B] Hydrogen Science and Engineering, 2 Volume Set: Materials, Processes, Systems, and Technology
Authored by 50 top academic, government and industry researchers, this handbook
explores mature, evolving technologies for a clean, economically viable alternative to non …
explores mature, evolving technologies for a clean, economically viable alternative to non …
Hydrogen: An energy carrier
MH McCay, S Shafiee - Future energy, 2020 - Elsevier
From an energy perspective, hydrogen is a very interesting material. While it is the smallest
molecule in the world with a very low volumetric energy density, it has a very high …
molecule in the world with a very low volumetric energy density, it has a very high …