Tuning Magnetic Anisotropy in Co (II) Tetrahedral Carbazole-Modified Phosphine Oxide Single-Ion Magnets: Importance of Structural Distortion versus Heavy-Ion …
Three mononuclear cobalt (II) tetrahedral complexes [Co (CzPh2PO) 2X2](CzPh2PO=(9H-
carbazol-9-yl) diphenylphosphine oxide and X= Cl (1), Br (2), I (3)) have been synthesized …
carbazol-9-yl) diphenylphosphine oxide and X= Cl (1), Br (2), I (3)) have been synthesized …
A new series of tetrahedral Co (ii) complexes [CoLX 2](X= NCS, Cl, Br, I) manifesting single-ion magnet features
A series of tetrahedral CoII complexes [CoLX2](X= NCS (1), Cl (2), Br (3) and I (4); L= 9, 9-
dimethyl-4, 5-bis (diphenylphosphino) xanthene) based on a P-donor ligand has been …
dimethyl-4, 5-bis (diphenylphosphino) xanthene) based on a P-donor ligand has been …
Investigation of easy-plane magnetic anisotropy in P-ligand square-pyramidal Co II single ion magnets
In this work we report two pentacoordinated CoII–P4X1 Single Ion Magnets (SIMs) based on
P-donor ligands. The tetradentate ligand tris [2-(diphenylphosphino) ethyl] phosphine allows …
P-donor ligands. The tetradentate ligand tris [2-(diphenylphosphino) ethyl] phosphine allows …
Magnetic anisotropy of two tetrahedral Co (II)-halide complexes with triphenylphosphine ligands
W Lv, HH Cui, L Chen, YQ Zhang, XT Chen… - Dalton …, 2022 - pubs.rsc.org
Recently, the choice of ligand and geometric control of mononuclear complexes, which can
affect the relaxation pathways and blocking temperature, have received wide attention in the …
affect the relaxation pathways and blocking temperature, have received wide attention in the …
Slow magnetic relaxation in Cobalt (II) field-induced single-ion magnets with positive large anisotropy
Three pentacoordinate complexes of the type [Co (pypz) X2], where pypz is a tridentate
ligand 2, 6-bis (pyrazol-1-yl) pyridine and X= Cl–(1), NCS–(2), and NCO–(3), have been …
ligand 2, 6-bis (pyrazol-1-yl) pyridine and X= Cl–(1), NCS–(2), and NCO–(3), have been …
Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co {(OPPh 2)(EPPh 2) N} 2], E= S, Se, explored by experimental and …
E Ferentinos, D Tzeli, S Sottini, EJJ Groenen… - Dalton …, 2023 - pubs.rsc.org
During the last few years, a large number of mononuclear Co (II) complexes of various
coordination geometries have been explored as potential single ion magnets (SIMs). In the …
coordination geometries have been explored as potential single ion magnets (SIMs). In the …
Structure, magnetic anisotropy and relaxation behavior of seven-coordinate Co (ii) single-ion magnets perturbed by counter-anions
G Yi, C Zhang, W Zhao, H Cui, L Chen, Z Wang… - Dalton …, 2020 - pubs.rsc.org
A series of mononuclear seven-coordinate Co (II) complexes [CoII (BPA-TPA)](ClO4) 2· H2O
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …
(2-ClO4),[CoII (BPA-TPA)](PF6) 2 (3-PF6) and [CoII (BPA-TPA)](BPh4) 2 (4-BPh4) have …
Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co (ii) single-ion magnets
B Zhang, Y Zhou, HY Huang, XL Zhang… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The mononuclear cobalt (II) complexes [Co (LN8)](BPh4) 2· C4H10O (1-BPh4) and [Co
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …
Trigonal prismatic cobalt (II) single-ion magnets: Manipulating the magnetic relaxation through symmetry control
Two mononuclear trigonal prismatic Co (II) complexes [Co (tppm*)][BPh4] 2 (1) and [Co
(hpy)][BPh4] 2· 3CH2Cl2 (2)(tppm*= 6, 6′, 6 ″-(methoxymethanetriyl) tris (2-(1 H-pyrazol-1 …
(hpy)][BPh4] 2· 3CH2Cl2 (2)(tppm*= 6, 6′, 6 ″-(methoxymethanetriyl) tris (2-(1 H-pyrazol-1 …
Field‐Induced Single‐Ion Magnetic Behavior in Two Mononuclear Cobalt (II) Complexes
Y Cui, Y Xu, X Liu, Y Li, BL Wang… - Chemistry–An Asian …, 2019 - Wiley Online Library
The employment of a new rigid N‐tridentate ligand, bis (1‐chloroimidazo [1, 5‐a] pyridin‐3‐
yl) pyridine (bcpp), in the construction of cobalt (II) single‐ion magnets is reported. Two …
yl) pyridine (bcpp), in the construction of cobalt (II) single‐ion magnets is reported. Two …