Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Strong exchange and magnetic blocking in N23−-radical-bridged lanthanide complexes

JD Rinehart, M Fang, WJ Evans, JR Long - Nature Chemistry, 2011 - nature.com
Single-molecule magnets approach the ultimate size limit for spin-based devices. These
complexes can retain spin information over long periods of time at low temperature …

Strategies towards single-chain magnets

HL Sun, ZM Wang, S Gao - Coordination Chemistry Reviews, 2010 - Elsevier
Single-chain magnets (SCM) are a novel class of molecular magnetic materials exhibiting
slow magnetic relaxation, which arises from large uniaxial type magnetic anisotropy, strong …

An organolanthanide building block approach to single-molecule magnets

KLM Harriman, M Murugesu - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) are highly sought after for their potential
application in high-density information storage, spintronics, and quantum computing. SMMs …

Rational design of single-molecule magnets: a supramolecular approach

T Glaser - Chemical Communications, 2011 - pubs.rsc.org
Since the discovery that Mn121212OAc acts as a single-molecule magnet (SMM), an
increasing number of transition metal complexes have been demonstrated to behave as …

Property‐Oriented Rational Design of Single‐Molecule Magnets: A C3‐Symmetric Mn6Cr Complex based on Three Molecular Building Blocks with a Spin Ground …

T Glaser, M Heidemeier, T Weyhermüller… - Angewandte Chemie …, 2006 - Wiley Online Library
Single-molecule magnets (SMMs) are a class of coordination compounds that attract
attention because of their magnetic bistability.[1] These finite-size molecules show a slow …

Large anisotropy barrier in a tetranuclear single-molecule magnet featuring low-coordinate cobalt centers

K Chakarawet, PC Bunting, JR Long - Journal of the American …, 2018 - ACS Publications
The tetranuclear cobalt cluster compound [Co4 (μ-NPtBu3) 4][B (C6F5) 4](tBu= tert-butyl)
was synthesized by chemical oxidation of Co4 (NPtBu3) 4 with [FeCp2][B (C6F5) 4] and …

Magnetic blocking in a linear iron(I) complex

JM Zadrozny, DJ Xiao, M Atanasov, GJ Long… - Nature …, 2013 - nature.com
Single-molecule magnets that contain one spin centre may represent the smallest possible
unit for spin-based computational devices. Such applications, however, require the …

A look at molecular nanosized magnets from the aspect of inter-molecular interactions

H Miyasaka, M Yamashita - Dalton Transactions, 2007 - pubs.rsc.org
Nanosized molecular magnetic materials such as single-molecule magnets and single-
chain magnets are recent attractive research targets in the fields of materials chemistry and …

Molecule-based magnets—an overview

JS Miller, AJ Epstein - MRS bulletin, 2000 - cambridge.org
Molecule-based magnets are a broad, emerging class of magnetic materials that expand the
materials properties typically associated with magnets to include low density, transparency …