3d single-ion magnets

GA Craig, M Murrie - Chemical Society Reviews, 2015 - pubs.rsc.org
One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Organic radicals, a promising route towards original molecule-based magnetic materials

C Train, L Norel, M Baumgarten - Coordination Chemistry Reviews, 2009 - Elsevier
We describe our activities on radical-based compounds developed within the 6-year priority
program of the DFG Schwerpunktprogramm “Molekularer Magnetismus”. During this period …

Significant enhancement of energy barriers in dinuclear dysprosium single-molecule magnets through electron-withdrawing effects

F Habib, G Brunet, V Vieru, I Korobkov… - Journal of the …, 2013 - ACS Publications
The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule
Magnets (SMMs) is investigated. By introducing highly electron-withdrawing atoms on …

[PDF][PDF] Enhancing magnetic hysteresis in single-molecule magnets by ligand functionalization

KX Yu, JGC Kragskow, YS Ding, YQ Zhai, D Reta… - Chem, 2020 - cell.com
Design criteria for dysprosium (III) single-molecule magnets (SMMs) with large thermal
energy barriers to magnetic reversal have been established and proven, and the challenge …

Electro-activity and magnetic switching in lanthanide-based single-molecule magnets

O Cador, B Le Guennic, F Pointillart - Inorganic Chemistry Frontiers, 2019 - pubs.rsc.org
The control of the single-molecule magnet (SMM) behaviour is highly challenging but crucial
to design molecular materials suitable for potential applications in molecular devices. To …

What is not required to make a single molecule magnet

F Neese, DA Pantazis - Faraday discussions, 2011 - pubs.rsc.org
The widely accepted assumption that the development of more efficient single molecule
magnets must involve ever higher total spin values has so far driven synthetic efforts towards …

A dinuclear cobalt complex featuring unprecedented anodic and cathodic redox switches for single-molecule magnet activity

S Fortier, JJ Le Roy, CH Chen, V Vieru… - Journal of the …, 2013 - ACS Publications
One-electron oxidation or reduction of the paramagnetic dinuclear Co (II) complex dmp2Nin
{Co [N (SiMe3) 2]} 2 (1; dmp2Nin2–= bis (2, 6-dimethylphenyl) nindigo), by fully reversible …

A Dimeric Manganese(III) Tetradentate Schiff Base Complex as a Single‐Molecule Magnet

H Miyasaka, R Clérac, W Wernsdorfer… - Angewandte Chemie …, 2004 - Wiley Online Library
2801 Angew. Chem. Int. Ed. 2004, 43, 2801–2805 DOI: 10.1002/anie. 200353563 2004
Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim multinuclear transition-metal complexes …

A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K

J Liu, YC Chen, JL Liu, V Vieru, L Ungur… - Journal of the …, 2016 - ACS Publications
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …