Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets

CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

[HTML][HTML] Electronic structure and magnetic anisotropy design of functional metal complexes

A Raza, M Perfetti - Coordination Chemistry Reviews, 2023 - Elsevier
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

[HTML][HTML] A series of tetraazalene radical-bridged M 2 (M= Cr III, Mn II, Fe II, Co II) complexes with strong magnetic exchange coupling

JA DeGayner, IR Jeon, TD Harris - Chemical Science, 2015 - pubs.rsc.org
The ability of tetraazalene radical bridging ligands to mediate exceptionally strong magnetic
exchange coupling across a range of transition metal complexes is demonstrated. The redox …

Single-Molecule Magnets:  A Large Mn30 Molecular Nanomagnet Exhibiting Quantum Tunneling of Magnetization

M Soler, W Wernsdorfer, K Folting, M Pink… - Journal of the …, 2004 - ACS Publications
The largest single-molecule magnet (SMM) to date has been prepared and studied.
Recrystallization of known [Mn12O12 (O2CCH2Bu t) 16 (H2O) 4](1; 8MnIII, 4MnIV) from …

A high anisotropy barrier in a sulfur‐bridged organodysprosium single‐molecule magnet

F Tuna, CA Smith, M Bodensteiner, L Ungur… - Angewandte …, 2012 - Wiley Online Library
Following the discovery in the early 1990s that individual molecules can exhibit slow
relaxation of magnetization and magnetic hysteresis,[1] studies of single-molecule magnets …

“Spin Tweaking” of a High‐Spin Molecule: An Mn25 Single‐Molecule Magnet with an S=61/2 Ground State

TC Stamatatos, KA Abboud… - Angewandte Chemie …, 2007 - Wiley Online Library
Polynuclear 3d metal complexes are of interest for various reasons, one of which is the
possibility that they might exhibit high-spin (S) ground states and easy-axis-type magnetic …

An organometallic single-ion magnet

SD Jiang, BW Wang, HL Sun, ZM Wang… - Journal of the American …, 2011 - ACS Publications
An organometallic single-ion magnet is synthesized with only 19 non-hydrogen atoms
featuring an erbium ion sandwiched by two different aromatic ligands. This molecule …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Molecular magnetism of lanthanide: Advances and perspectives

Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019 - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …

Molecular spintronics using single-molecule magnets

L Bogani, W Wernsdorfer - Nature materials, 2008 - nature.com
A revolution in electronics is in view, with the contemporary evolution of the two novel
disciplines of spintronics and molecular electronics. A fundamental link between these two …