Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

FS Guo, BM Day, YC Chen, ML Tong, A Mansikkamäki… - Science, 2018 - science.org
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

A Trinuclear Radical‐Bridged Lanthanide Single‐Molecule Magnet

CA Gould, LE Darago, MI Gonzalez… - Angewandte Chemie …, 2017 - Wiley Online Library
Assembly of the triangular, organic radical‐bridged complexes Cp* 6Ln3 (μ3‐HAN)(Cp*=
pentamethylcyclopentadienyl; Ln= Gd, Tb, Dy; HAN= hexaazatrinaphthylene) proceeds …

Lanthanide single molecule magnets: progress and perspective

P Zhang, L Zhang, J Tang - Dalton Transactions, 2015 - pubs.rsc.org
The last few years have seen a huge renaissance in the study of single molecule magnets
(SMMs) thanks to the extensive applications of lanthanide ions with large inherent …

Magnetic memory in an isotopically enriched and magnetically isolated mononuclear dysprosium complex

F Pointillart, K Bernot, S Golhen… - Angewandte …, 2015 - Wiley Online Library
The influence of nuclear spin on the magnetic hysteresis of a single‐molecule is evidenced.
Isotopically enriched DyIII complexes are synthesized and an isotopic dependence of their …

Fine‐tuning the local symmetry to attain record blocking temperature and magnetic remanence in a single‐ion magnet

L Ungur, JJ Le Roy, I Korobkov… - Angewandte …, 2014 - Wiley Online Library
Remanence and coercivity are the basic characteristics of permanent magnets. They are
also tightly correlated with the existence of long relaxation times of magnetization in a …

Polymorphism in a cobalt-based single-ion magnet tuning its barrier to magnetization relaxation

AA Pavlov, YV Nelyubina, SV Kats… - The journal of …, 2016 - ACS Publications
A large barrier to magnetization reversal, a signature of a good single-molecule magnet
(SMM), strongly depends on the structural environment of a paramagnetic metal ion. In a …

Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K

Z Zhu, C Zhao, T Feng, X Liu, X Ying, XL Li… - Journal of the …, 2021 - ACS Publications
Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2014 - Elsevier
A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

Equatorially coordinated lanthanide single ion magnets

P Zhang, L Zhang, C Wang, S Xue… - Journal of the …, 2014 - ACS Publications
The magnetic relaxation dynamics of low-coordinate DyIII and ErIII complexes, namely three-
coordinate ones with an equatorially coordinated triangle geometry and five-coordinate …

Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets

W Wernsdorfer, N Aliaga-Alcalde, DN Hendrickson… - Nature, 2002 - nature.com
Various present and future specialized applications of magnets require monodisperse, small
magnetic particles, and the discovery of molecules that can function as nanoscale magnets …