Metallocenes represent one of the most important classes of organometallics with wide
prospects for practical use in various fields of chemistry, materials science, molecular …

Metallocenes represent archetypical organometallic compounds playing key roles in various
fields of fundamental and applied chemistry. Many of their unique properties arise from low …

Electron impact (EI) ionization mass spectra, metastable-ion decays and appearance
energies are reported for the title compounds. Gas-phase formation enthalpies (Δ Hf) and …

Multiphoton ionization and dissociation of Mn2 (CO) 10 is reported at 351, 248 and 193 nm
in comparison with electron impact ionization. In the case of electron impact ionization, two …

Since the discovery of ferrocene 60 years ago,[1] metallocenes have represented one of the
most intriguing classes of organometallics. Numerous theoretical and experimental …

Charge stripping experiments indicate that in the reaction M+→ M2+ e− the doublycharged
transition-metal ions M2+ (M= Fe, Co, Ni) are formed in excited states. Introduction of one or …

A protonation/deprotonation mechanism has been established for the interpretation of ions
in MALDI. We show herein that negative ions can be generated in different ways. Molecules …

Electron impact (EI) and multiphoton ionization (MPI) mass spectra of CpMo (CO) 2NO (Cp
C5H5, cyclopentadienyl ligand) are reported. The ionization energy (8.20 eV) and …

For the first time the crystal structure of a permethylated metallocene anion has been
obtained. The 17 valence electron complex decamethylmanganocene Cp* 2Mn is reduced …

Metallocene ions (Cp2M+, M= Cr, Co, Ni) were studied by threshold photoelectron photoion
coincidence spectroscopy (TPEPICO) to investigate the mechanism, energetics, and kinetics …