Two mononuclear cobalt (II) complexes, with the formulas [Co (2, 6-dfba) 2 (bpp) 2 (H2O) 2]
n (1) and [Co (2, 6-dfba) 2 (bpe) 2 (H2O) 2] n (2)(2, 6-Hdfba= 2, 6-difluorobenzoic acid, bpp …

A tetranuclear cubane-type complex [Co4 (ntfa) 4 (CH3O) 4 (CH3OH) 4](1) with a {Co4O4}
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …

Understanding magnetic anisotropy and specifically how to tailor it is crucial in the search for
high-temperature single-ion magnets. Herein, we investigate the magnetic anisotropy in a …

For single-ion magnets (SIMs), understanding the effects of the local coordination
environment and ligand field on magnetic anisotropy is key to controlling their magnetic …

The mononuclear cobalt (II) complexes [Co (LN8)](BPh4) 2· C4H10O (1-BPh4) and [Co
(LN8)](NO3) 2· CH3CN (2-NO3)(LN8= 1, 4, 7, 10-tetrakis (2-pyridinemethyl)-1, 4, 7, 10 …

We herein reported the synthetic, structural, computational, and magnetic studies of four air-
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …

Comprehensive Summary Precise modulation of the magnetic anisotropy of metal ions
remains highly important for the development of high–performance single‐molecule …

By elaborately employing a rigid tetrazo macrocyclic ligand, both the designed Co (II)
complexes [Co (12-TMC) Py](BF4) 2 (1) and [Co (12-TMC) DMF](BF4) Cl (2)(12-TMC= 1, 4 …

The present study reveals that predetermined diverse topology and desired properties can
be achieved by strategically designing the ligand and it confirms that the structural and …

In this work, the effects of ligand field strength as well as the metal coordination geometry on
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …