Non-isothermal cure and exfoliation of tri-functional epoxy-clay nanocomposites

F Shiravand, JM Hutchinson… - Express polymer …, 2015 - upcommons.upc.edu
The non-isothermal cure kinetics of polymer silicate layered nanocomposites based on a tri-
functional epoxy resin has been investigated by differential scanning calorimetry. From an …

Analysis of the cure of epoxy based layered silicate nanocomposites: reaction kinetics and nanostructure development

S Montserrat, F Román, JM Hutchinson… - Journal of Applied …, 2008 - Wiley Online Library
The cure reaction kinetics of epoxy resin, with organically modified montmorillonite loadings
of up to 20 wt% and with stoichiometric conditions, has been studied by differential scanning …

On the effect of montmorillonite in the curing reaction of epoxy nanocomposites

F Román, S Montserrat, JM Hutchinson - Journal of Thermal Analysis and …, 2007 - Springer
The procedure for the fabrication of epoxy-based polymer layered silicate nanocomposites
is important in respect of the nanostructure that is developed. To further our understanding of …

Intra‐and extra‐gallery reactions in tri‐functional epoxy polymer layered silicate nanocomposites

JM Hutchinson, F Shiravand… - Journal of applied …, 2013 - Wiley Online Library
Achieving a high degree of exfoliation in epoxy‐based polymer layered silicate (PLS)
nanocomposites is crucial to their successful industrial application, but has hitherto proved …

Identification of nanostructural development in epoxy polymer layered silicate nanocomposites from the interpretation of differential scanning calorimetry and dielectric …

F Román, Y Calventus, P Colomer, JM Hutchinson - Thermochimica acta, 2012 - Elsevier
The effect of nanoclay on the non-isothermal cure kinetics of polymer layered silicate
nanocomposites based upon epoxy resin is studied by calorimetric techniques (DSC and …

Comparative results between three protocols for achieving highly exfoliated epoxy-clay nanocomposites

JM Hutchinson, F Shiravand, Y Calventus… - Polimery, 2014 - polimery.ichp.vot.pl
Three different methods of fabricating polymer layered silicate (PLS) nanocomposites based
upon a tri-functional epoxy resin are compared in respect of the nanostructure and impact …

Homopolymerization effects in polymer layered silicate nanocomposites based upon epoxy resin: Implications for exfoliation

P Pustkova, JM Hutchinson, F Román… - Journal of Applied …, 2009 - Wiley Online Library
Exfoliation of polymer layered silicate nanocomposites based upon epoxy resin has
previously been reported to be enhanced by allowing some homopolymerization of the resin …

Isothermal curing of polymer layered silicate nanocomposites based upon epoxy resin by means of anionic homopolymerisation

F Román, Y Calventus, P Colomer, JM Hutchinson - Thermochimica acta, 2013 - Elsevier
The use of an initiator, 4-(dimethylamino) pyridine (DMAP), to promote an anionic
homopolymerisation reaction for the isothermal cure of polymer layered silicate (PLS) …

Synthesis of epoxy–clay nanocomposites. Influence of the nature of the curing agent on structure

X Kornmann, H Lindberg, LA Berglund - Polymer, 2001 - Elsevier
Epoxy–clay nanocomposites were synthesised by swelling an organophilic montmorillonite
in a diglycidyl ether of bisphenol A resin with subsequent polymerisation. Three different …

Layered silicate nanocomposites based on various high‐functionality epoxy resins: The influence of an organoclay on resin cure

O Becker, GP Simon, RJ Varley… - Polymer Engineering & …, 2003 - Wiley Online Library
The influence of an organically modified clay on the curing behavior of three epoxy systems
widely used in the aerospace industry and of different structures and functionalities was …