Oriented crystal growth on organic monolayers

JH Harding, CL Freeman, DM Duffy - CrystEngComm, 2014 - pubs.rsc.org
Ordered organic substrates influence the crystallisation of minerals and different crystal
morphologies and polymorphs can be stabilised by varying the properties of the substrates …

Cooperative reorganization of mineral and template during directed nucleation of calcium carbonate

JRI Lee, TYJ Han, TM Willey, MH Nielsen… - The Journal of …, 2013 - ACS Publications
Self-assembled monolayers (SAMs) prepared from organic thiol molecules on metal
substrates are known to exert substantial influence over mineralization and, as such, provide …

Template induced crystallization of biominerals on self-assembled monolayers of alkylthiols

J Küther, W Tremel - Thin Solid Films, 1998 - Elsevier
We have studied the templated crystallization of the three polymorphs of calcium carbonate
on self-assembled monolayers of ω-substituted alkylthiols on gold surfaces. Our interest has …

Modelling the interfaces between calcite crystals and Langmuir monolayers

DM Duffy, JH Harding - Journal of Materials Chemistry, 2002 - pubs.rsc.org
Langmuir monolayers are good model systems for investigating the use of organic templates
to control the growth and morphology of calcium carbonate. We investigate the structure of …

Calcite shape modulation through the lattice mismatch between the self-assembled monolayer template and the nucleated crystal face

B Pokroy, J Aizenberg - CrystEngComm, 2007 - pubs.rsc.org
The shapes of biologically formed calcite crystals are extremely versatile. Numerous studies
have addressed the possible biological mechanism of crystal shape regulation. Synthetic …

Structural adaptability in an organic template for CaCO 3 mineralization

E DiMasi, SY Kwak, BP Pichon, NAJM Sommerdijk - CrystEngComm, 2007 - pubs.rsc.org
Biomimetic strategies to control mineral nucleation include the development of self-
assembled monolayers with appropriate structural properties. We present a bis-urea based …

Crystallization in patterns: a bio‐inspired approach

J Aizenberg - Advanced Materials, 2004 - Wiley Online Library
Nature produces a wide variety of exquisite, highly functional mineralized tissues using
simple inorganic salts. Biomineralization occurs within specific microenvironments, and is …

Crystal engineering of inorganic materials at organized organic surfaces

S Mann, BR Heywood, S Rajam, JBA Walker - 1991 - ACS Publications
The nucleation and growth of the mineral, CaCO3, under compressed Langmuir monolayers
has been studied by optical and electron microscopy and electron diffraction. The structure …

A bio-inspired approach to controlled crystallization at the nanoscale

J Aizenberg - Bell Labs Technical Journal, 2005 - ieeexplore.ieee.org
Nature produces a wide variety of exquisite mineralized tissues fulfilling diverse functions,
often from simple inorganic salts. Organisms exercise a level of molecular control over the …

The crystallisation of calcite clusters on self-assembled monolayers

DM Duffy, JH Harding - Surface science, 2005 - Elsevier
We use simulations to investigate the crystallisation of amorphous nanoparticles by organic
monolayers. A simplified model of the system is used to permit the simulation of the …